Spin Trapping of Molecules Adsorbed on Zinc Oxide

T MATSUZAKI, T UDA, A KAZUSAKA, G W KEULKS, Russell Francis Howe

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The reactions of the spin trap PBN with hydrogen and propylene adsorbed on ZnO are reported. For hydrogen, evidence is presented that the species trapped are H atoms adsorbed on Zn sites. For propylene, the allyl anion adsorbed on Zn sites reacts with PBN, but the resulting hydroxylamine must be oxidized before a nitroxide radical can be observed. Less than 1% of the adsorbed species are detected by the spin trapping technique.
Original languageEnglish
Pages (from-to)7511-7513
Number of pages3
JournalJournal of the American Chemical Society
Volume102
Issue number25
DOIs
Publication statusPublished - 1980

Cite this

Spin Trapping of Molecules Adsorbed on Zinc Oxide. / MATSUZAKI, T ; UDA, T ; KAZUSAKA, A ; KEULKS, G W ; Howe, Russell Francis.

In: Journal of the American Chemical Society, Vol. 102, No. 25, 1980, p. 7511-7513.

Research output: Contribution to journalArticle

MATSUZAKI, T, UDA, T, KAZUSAKA, A, KEULKS, GW & Howe, RF 1980, 'Spin Trapping of Molecules Adsorbed on Zinc Oxide', Journal of the American Chemical Society, vol. 102, no. 25, pp. 7511-7513. https://doi.org/10.1021/ja00545a019
MATSUZAKI, T ; UDA, T ; KAZUSAKA, A ; KEULKS, G W ; Howe, Russell Francis. / Spin Trapping of Molecules Adsorbed on Zinc Oxide. In: Journal of the American Chemical Society. 1980 ; Vol. 102, No. 25. pp. 7511-7513.
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