Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene

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Abstract

C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.

Original languageEnglish
Pages (from-to)1040-1044
Number of pages5
JournalSynthesis
Volume6
DOIs
Publication statusPublished - 2006

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Alkenes
Dimers
Olefins
Ligands
Electrons
formal glycol
carbene

Keywords

  • electron-rich olefin dimer
  • imidazolidinylidene
  • chiral
  • C-2-symmetric
  • heterocyclic carbene ligands
  • ruthenium catalysts
  • olefin metathesis
  • metal-complexes
  • derivatives
  • palladium

Cite this

@article{93194ecd1a8544888957a3060ba636bc,
title = "Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene",
abstract = "C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.",
keywords = "electron-rich olefin dimer, imidazolidinylidene, chiral, C-2-symmetric, heterocyclic carbene ligands, ruthenium catalysts, olefin metathesis, metal-complexes, derivatives, palladium",
author = "C Marshall and Ward, {M F} and Skakle, {J M S}",
year = "2006",
doi = "10.1055/s-2006-926361",
language = "English",
volume = "6",
pages = "1040--1044",
journal = "Synthesis",
issn = "0039-7881",
publisher = "GEORG THIEME VERLAG KG",

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T1 - Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene

AU - Marshall, C

AU - Ward, M F

AU - Skakle, J M S

PY - 2006

Y1 - 2006

N2 - C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.

AB - C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.

KW - electron-rich olefin dimer

KW - imidazolidinylidene

KW - chiral

KW - C-2-symmetric

KW - heterocyclic carbene ligands

KW - ruthenium catalysts

KW - olefin metathesis

KW - metal-complexes

KW - derivatives

KW - palladium

U2 - 10.1055/s-2006-926361

DO - 10.1055/s-2006-926361

M3 - Article

VL - 6

SP - 1040

EP - 1044

JO - Synthesis

JF - Synthesis

SN - 0039-7881

ER -