Strontium manganese diselenite, SrMn(SeO3)(2), containing unusual MnO5+1 polyhedra

Magnus G. Johnston, William T. A. Harrison

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7 Citations (Scopus)

Abstract

Hydrothermally prepared SrMn(SeO3)(2) contains infinite chains of vertex-sharing irregular MnO5+1 polyhedra [mean Mn-O 2.226 (3) Angstrom], which are fused into layers via pyramidal SeO3 groups [mean Se-O 1.698 (3) Angstrom]. Nine-coordinate Sr2+ cations [mean Sr-O 2.715 (4) Angstrom] complete the layered structure.

Original languageEnglish
Pages (from-to)i33-i34
Number of pages2
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC58
DOIs
Publication statusPublished - 2002

Cite this

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title = "Strontium manganese diselenite, SrMn(SeO3)(2), containing unusual MnO5+1 polyhedra",
abstract = "Hydrothermally prepared SrMn(SeO3)(2) contains infinite chains of vertex-sharing irregular MnO5+1 polyhedra [mean Mn-O 2.226 (3) Angstrom], which are fused into layers via pyramidal SeO3 groups [mean Se-O 1.698 (3) Angstrom]. Nine-coordinate Sr2+ cations [mean Sr-O 2.715 (4) Angstrom] complete the layered structure.",
author = "Johnston, {Magnus G.} and Harrison, {William T. A.}",
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doi = "10.1107/S0108270102001208",
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journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
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T1 - Strontium manganese diselenite, SrMn(SeO3)(2), containing unusual MnO5+1 polyhedra

AU - Johnston, Magnus G.

AU - Harrison, William T. A.

PY - 2002

Y1 - 2002

N2 - Hydrothermally prepared SrMn(SeO3)(2) contains infinite chains of vertex-sharing irregular MnO5+1 polyhedra [mean Mn-O 2.226 (3) Angstrom], which are fused into layers via pyramidal SeO3 groups [mean Se-O 1.698 (3) Angstrom]. Nine-coordinate Sr2+ cations [mean Sr-O 2.715 (4) Angstrom] complete the layered structure.

AB - Hydrothermally prepared SrMn(SeO3)(2) contains infinite chains of vertex-sharing irregular MnO5+1 polyhedra [mean Mn-O 2.226 (3) Angstrom], which are fused into layers via pyramidal SeO3 groups [mean Se-O 1.698 (3) Angstrom]. Nine-coordinate Sr2+ cations [mean Sr-O 2.715 (4) Angstrom] complete the layered structure.

U2 - 10.1107/S0108270102001208

DO - 10.1107/S0108270102001208

M3 - Article

VL - C58

SP - i33-i34

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -