Structural relationships in the homologous series of alkyltriphenylstannane compounds of formula Ph3Sn(CH2)n-1CH3, with n even and in the range 4-14 and 18

G. M. Allan, Robert Alan Howie, Janet Mabel Scott Skakle, J. L. Wardell, S. M. S. V. Wardell

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The solid state structures of several compounds in the homologous series of alkyltriphenylstannanes of general formula Ph3Sn(CH2)(n-1)CH3 have been determined. For it in the range 4-10 the structures are monoclinic with space group P21/c. For n greater than 10 they are, instead, triclinic with space group P (1) over bar. The structural difference between the two classes is attributable to a change in the degree of control over the packing of the molecules exerted by the triphenylstannyl entity on the one hand and the alkyl chain on the other. (c) 2005 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)695-701
Number of pages6
JournalPolyhedron
Volume25
DOIs
Publication statusPublished - 2006

Keywords

  • alkyltriphenylstannane
  • homologous series
  • X-ray structures
  • CRYSTAL
  • DATABASE

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