STUDY OF THE MECHANISM OF HIGHER ALCOHOL SYNTHESIS ON CU-ZNO-AL2O3 CATALYSTS BY CATALYTIC TESTS, PROBE MOLECULES, AND TEMPERATURE PROGRAMMED DESORPTION STUDIES

A  KIENNEMANN; Hicham Idriss; R  KIEFFER; P  CHAUMETTE; D  DURAND

STUDY OF THE MECHANISM OF HIGHER ALCOHOL SYNTHESIS ON CU-ZNO-AL2O3 CATALYSTS BY CATALYTIC TESTS, PROBE MOLECULES, AND TEMPERATURE PROGRAMMED DESORPTION STUDIES

A KIENNEMANN, Hicham Idriss, R KIEFFER, P CHAUMETTE, D DURAND

Chemistry

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

In addition to catalytic tests, the addition of probe molecules (methanol, formaldehyde, ethylene glycol, ethanol, acetone, propionaldehyde) and thermoprogrammed-desorption studies (formaldehyde, acetaldehyde, ethanol, acetone) have been used to investigate the mechanism of higher alcohol synthesis on Cu-ZnO-Al2O3 catalysts. More attention is given to the first carbon-carbon bond and branched-product formation. An overall mechanism is proposed.

Original language	English
Pages (from-to)	1130-1138
Number of pages	9
Journal	Industrial Relations
Volume	30
Issue number	6
Publication status	Published - Jun 1991

Keywords

CESIUM-DOPED CU/ZNO
OXYGENATE SYNTHESIS
SURFACE-REACTIONS
CO HYDROGENATION
CARBON-MONOXIDE
OXIDE CATALYSTS
ACETIC-ACID
ZINC-OXIDE
METHANOL
ADSORPTION

Cite this

@article{4419fe8cc674468ca8775e772b0193f9,

title = "STUDY OF THE MECHANISM OF HIGHER ALCOHOL SYNTHESIS ON CU-ZNO-AL2O3 CATALYSTS BY CATALYTIC TESTS, PROBE MOLECULES, AND TEMPERATURE PROGRAMMED DESORPTION STUDIES",

abstract = "In addition to catalytic tests, the addition of probe molecules (methanol, formaldehyde, ethylene glycol, ethanol, acetone, propionaldehyde) and thermoprogrammed-desorption studies (formaldehyde, acetaldehyde, ethanol, acetone) have been used to investigate the mechanism of higher alcohol synthesis on Cu-ZnO-Al2O3 catalysts. More attention is given to the first carbon-carbon bond and branched-product formation. An overall mechanism is proposed.",

keywords = "CESIUM-DOPED CU/ZNO, OXYGENATE SYNTHESIS, SURFACE-REACTIONS, CO HYDROGENATION, CARBON-MONOXIDE, OXIDE CATALYSTS, ACETIC-ACID, ZINC-OXIDE, METHANOL, ADSORPTION",

author = "A KIENNEMANN and Hicham Idriss and R KIEFFER and P CHAUMETTE and D DURAND",

year = "1991",

month = jun,

language = "English",

volume = "30",

pages = "1130--1138",

journal = "Industrial Relations",

issn = "0019-8676",

publisher = "Wiley-Blackwell",

number = "6",

}

TY - JOUR

T1 - STUDY OF THE MECHANISM OF HIGHER ALCOHOL SYNTHESIS ON CU-ZNO-AL2O3 CATALYSTS BY CATALYTIC TESTS, PROBE MOLECULES, AND TEMPERATURE PROGRAMMED DESORPTION STUDIES

AU - KIENNEMANN, A

AU - Idriss, Hicham

AU - KIEFFER, R

AU - CHAUMETTE, P

AU - DURAND, D

PY - 1991/6

Y1 - 1991/6

N2 - In addition to catalytic tests, the addition of probe molecules (methanol, formaldehyde, ethylene glycol, ethanol, acetone, propionaldehyde) and thermoprogrammed-desorption studies (formaldehyde, acetaldehyde, ethanol, acetone) have been used to investigate the mechanism of higher alcohol synthesis on Cu-ZnO-Al2O3 catalysts. More attention is given to the first carbon-carbon bond and branched-product formation. An overall mechanism is proposed.

AB - In addition to catalytic tests, the addition of probe molecules (methanol, formaldehyde, ethylene glycol, ethanol, acetone, propionaldehyde) and thermoprogrammed-desorption studies (formaldehyde, acetaldehyde, ethanol, acetone) have been used to investigate the mechanism of higher alcohol synthesis on Cu-ZnO-Al2O3 catalysts. More attention is given to the first carbon-carbon bond and branched-product formation. An overall mechanism is proposed.

KW - CESIUM-DOPED CU/ZNO

KW - OXYGENATE SYNTHESIS

KW - SURFACE-REACTIONS

KW - CO HYDROGENATION

KW - CARBON-MONOXIDE

KW - OXIDE CATALYSTS

KW - ACETIC-ACID

KW - ZINC-OXIDE

KW - METHANOL

KW - ADSORPTION

M3 - Article

SN - 0019-8676

VL - 30

SP - 1130

EP - 1138

JO - Industrial Relations

JF - Industrial Relations

IS - 6

ER -

STUDY OF THE MECHANISM OF HIGHER ALCOHOL SYNTHESIS ON CU-ZNO-AL2O3 CATALYSTS BY CATALYTIC TESTS, PROBE MOLECULES, AND TEMPERATURE PROGRAMMED DESORPTION STUDIES

Abstract

Keywords

Fingerprint

Cite this