Subsolidus relations in the BaO-La2O3-V2O5 phase diagram

M. G. Skellern, Janet Mabel Scott Skakle

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The subsolidus region of the BaO-La2O3-V2O5 phase diagram has been redetermined. Previously reported binary phases of LaVO4, La8V2O17, La3VO7, BaLa2O4, Ba3V2O8, Ba2V2O7, Ba3V4O13 and BaV2O6 have all been confirmed. The ternary phases Ba2LaV3O11, Ba3LaV3O12 and Ba3La40V12O93 have also been confirmed. The new phase "BaLa10V4O26" has been synthesised for the first time and is reported here along with the amended phase diagram. The previously omitted phase of La1.42V0.58O3.58 has also been included and reasons for this are cited. The diagram is shown for two temperatures (1000 and 600 degreesC) due to the low melting point of V2O5-rich compounds. (C) 2002 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)2933-2937
Number of pages4
JournalJournal of the European Ceramic Society
Volume22
DOIs
Publication statusPublished - 2002

Keywords

  • electron microscopy
  • phase diagram
  • powders-solid state reaction
  • transition metal oxides
  • X-ray methods
  • BaO-La2O3-VzO(5)
  • CRYSTAL-STRUCTURES
  • EQUILIBRIA

Cite this

Subsolidus relations in the BaO-La2O3-V2O5 phase diagram. / Skellern, M. G.; Skakle, Janet Mabel Scott.

In: Journal of the European Ceramic Society, Vol. 22, 2002, p. 2933-2937.

Research output: Contribution to journalArticle

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title = "Subsolidus relations in the BaO-La2O3-V2O5 phase diagram",
abstract = "The subsolidus region of the BaO-La2O3-V2O5 phase diagram has been redetermined. Previously reported binary phases of LaVO4, La8V2O17, La3VO7, BaLa2O4, Ba3V2O8, Ba2V2O7, Ba3V4O13 and BaV2O6 have all been confirmed. The ternary phases Ba2LaV3O11, Ba3LaV3O12 and Ba3La40V12O93 have also been confirmed. The new phase {"}BaLa10V4O26{"} has been synthesised for the first time and is reported here along with the amended phase diagram. The previously omitted phase of La1.42V0.58O3.58 has also been included and reasons for this are cited. The diagram is shown for two temperatures (1000 and 600 degreesC) due to the low melting point of V2O5-rich compounds. (C) 2002 Elsevier Science Ltd. All rights reserved.",
keywords = "electron microscopy, phase diagram, powders-solid state reaction, transition metal oxides, X-ray methods, BaO-La2O3-VzO(5), CRYSTAL-STRUCTURES, EQUILIBRIA",
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AU - Skakle, Janet Mabel Scott

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N2 - The subsolidus region of the BaO-La2O3-V2O5 phase diagram has been redetermined. Previously reported binary phases of LaVO4, La8V2O17, La3VO7, BaLa2O4, Ba3V2O8, Ba2V2O7, Ba3V4O13 and BaV2O6 have all been confirmed. The ternary phases Ba2LaV3O11, Ba3LaV3O12 and Ba3La40V12O93 have also been confirmed. The new phase "BaLa10V4O26" has been synthesised for the first time and is reported here along with the amended phase diagram. The previously omitted phase of La1.42V0.58O3.58 has also been included and reasons for this are cited. The diagram is shown for two temperatures (1000 and 600 degreesC) due to the low melting point of V2O5-rich compounds. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - The subsolidus region of the BaO-La2O3-V2O5 phase diagram has been redetermined. Previously reported binary phases of LaVO4, La8V2O17, La3VO7, BaLa2O4, Ba3V2O8, Ba2V2O7, Ba3V4O13 and BaV2O6 have all been confirmed. The ternary phases Ba2LaV3O11, Ba3LaV3O12 and Ba3La40V12O93 have also been confirmed. The new phase "BaLa10V4O26" has been synthesised for the first time and is reported here along with the amended phase diagram. The previously omitted phase of La1.42V0.58O3.58 has also been included and reasons for this are cited. The diagram is shown for two temperatures (1000 and 600 degreesC) due to the low melting point of V2O5-rich compounds. (C) 2002 Elsevier Science Ltd. All rights reserved.

KW - electron microscopy

KW - phase diagram

KW - powders-solid state reaction

KW - transition metal oxides

KW - X-ray methods

KW - BaO-La2O3-VzO(5)

KW - CRYSTAL-STRUCTURES

KW - EQUILIBRIA

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JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

SN - 0955-2219

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