Sulfur as a catalyst promoter or selectivity modifier in heterogeneous catalysis

Alan J. McCue, James A. Anderson

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

For most heterogeneous catalysts adsorbed sulfur and sulphur-containing molecules are generally regarded as a poison. However, a growing number of reports from academia and industry demonstrate that sulfur may act as an activity promoter or selectivity modifier in heterogeneous catalysis. Reports from a variety of areas such as Fischer-Tropsch synthesis, catalytic reforming, regio and chemoselective hydrogenation as well as CO oxidation, hydrocarbon oxidation and NO reduction are discussed. Based on the literature cited, comments on the levels of sulfur necessary to observe a promotional effect are suggested/proposed, as well as some of the techniques which can be applied to understand such effects. This journal is
Original languageEnglish
Pages (from-to)272-294
Number of pages23
JournalCatalysis Science & Technology
Volume4
Issue number2
Early online date6 Dec 2013
DOIs
Publication statusPublished - 1 Feb 2014

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Catalyst selectivity
Sulfur
Catalysis
Catalysts
Catalytic reforming
Oxidation
Fischer-Tropsch synthesis
Poisons
Carbon Monoxide
Hydrocarbons
Hydrogenation
Catalyst activity
Molecules
Industry

Cite this

Sulfur as a catalyst promoter or selectivity modifier in heterogeneous catalysis. / McCue, Alan J.; Anderson, James A.

In: Catalysis Science & Technology, Vol. 4, No. 2, 01.02.2014, p. 272-294.

Research output: Contribution to journalArticle

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