Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative

M. John Plater, William T. A. Harrison, Henry S. Rzepa

Research output: Contribution to journal › Article

7 Citations (Scopus)
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Abstract

Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.
Original languageEnglish
Pages (from-to)711-718
Number of pages8
JournalJournal of Chemical Research
Volume39
Issue number12
Early online date1 Dec 2015
DOIs
Publication statusPublished - 1 Dec 2015

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Chromophores
Ethanol
Crystal structure
Derivatives
Density functional theory
picric acid

Keywords

  • aniline
  • mauve
  • mauveine
  • N-phenyl-p-phenylediamine
  • William Henry Perkin

Cite this

Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate : the first crystal structures of a mauveine chromophore and a synthetic derivative. / Plater, M. John; Harrison, William T. A.; Rzepa, Henry S. .

In: Journal of Chemical Research, Vol. 39, No. 12, 01.12.2015, p. 711-718.

Research output: Contribution to journal › Article

Plater, MJ, Harrison, WTA & Rzepa, HS 2015, 'Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative', Journal of Chemical Research, vol. 39, no. 12, pp. 711-718. https://doi.org/10.3184/174751915X14474318419130
Plater MJ, Harrison WTA, Rzepa HS. Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative. Journal of Chemical Research. 2015 Dec 1;39(12):711-718. https://doi.org/10.3184/174751915X14474318419130
Plater, M. John ; Harrison, William T. A. ; Rzepa, Henry S. . / Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate : the first crystal structures of a mauveine chromophore and a synthetic derivative. In: Journal of Chemical Research. 2015 ; Vol. 39, No. 12. pp. 711-718.
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Access to Document

  • JCR mauveine ACCEPTED SupplementaryAccepted author manuscript, 5.91 MB
  • Accepted Manuscript

    This is an Accepted Manuscript of an article published by Science reviews 2000 Ltd in Journal of Chemical Research in December 2015, available online: http://dx.doi.org/10.3184/174751915X14474318419130.

    Accepted author manuscript, 10 MB