Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative

M. John Plater; William T. A. Harrison; Henry S.  Rzepa

doi:10.3184/174751915X14474318419130

Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative

M. John Plater, William T. A. Harrison, Henry S. Rzepa

Research output: Contribution to journal › Article

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Abstract

Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.

Original language	English
Pages (from-to)	711-718
Number of pages	8
Journal	Journal of Chemical Research
Volume	39
Issue number	12
Early online date	1 Dec 2015
DOIs	https://doi.org/10.3184/174751915X14474318419130
Publication status	Published - 1 Dec 2015

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Keywords

aniline
mauve
mauveine
N-phenyl-p-phenylediamine
William Henry Perkin

Cite this

Plater, M. J., Harrison, W. T. A., & Rzepa, H. S. (2015). Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative. Journal of Chemical Research, 39(12), 711-718. https://doi.org/10.3184/174751915X14474318419130

Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate : the first crystal structures of a mauveine chromophore and a synthetic derivative. / Plater, M. John ; Harrison, William T. A.; Rzepa, Henry S. .

In: Journal of Chemical Research, Vol. 39, No. 12, 01.12.2015, p. 711-718.

Research output: Contribution to journal › Article

Plater, MJ , Harrison, WTA & Rzepa, HS 2015, 'Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative', Journal of Chemical Research, vol. 39, no. 12, pp. 711-718. https://doi.org/10.3184/174751915X14474318419130

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abstract = "Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.",

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author = "Plater, {M. John} and Harrison, {William T. A.} and Rzepa, {Henry S.}",

note = "We thank the EPSRC National Mass Spectrometry Service Centre (University of Swansea) for measuring mass spectra and the EPSRC National Crystallography Service Centre (University of Southampton) for collecting the diffraction data.",

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JCR mauveine ACCEPTED SupplementaryAccepted author manuscript, 5.91 MB
Accepted Manuscript
This is an Accepted Manuscript of an article published by Science reviews 2000 Ltd in Journal of Chemical Research in December 2015, available online: http://dx.doi.org/10.3184/174751915X14474318419130.
Accepted author manuscript, 10 MB