Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative

M. John Plater; William T. A. Harrison; Henry S.  Rzepa

doi:10.3184/174751915X14474318419130

Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative

M. John Plater, William T. A. Harrison, Henry S. Rzepa

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

8 Downloads (Pure)

Abstract

Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.

Original language	English
Pages (from-to)	711-718
Number of pages	8
Journal	Journal of Chemical Research
Volume	39
Issue number	12
Early online date	1 Dec 2015
DOIs	https://doi.org/10.3184/174751915X14474318419130
Publication status	Published - 1 Dec 2015

Keywords

aniline
mauve
mauveine
N-phenyl-p-phenylediamine
William Henry Perkin

Access to Document

10.3184/174751915X14474318419130Licence: Unspecified

JCR mauveine ACCEPTED SupplementaryAccepted author manuscript, 5.91 MB
Accepted Manuscript
This is an Accepted Manuscript of an article published by Science reviews 2000 Ltd in Journal of Chemical Research in December 2015, available online: http://dx.doi.org/10.3184/174751915X14474318419130.
Accepted author manuscript, 10 MB

Fingerprint Dive into the research topics of 'Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative'. Together they form a unique fingerprint.

Michael Plater
- Chemistry (Research Theme)
- School of Natural & Computing Sciences, Chemistry - Senior Lecturer
Person: Academic

Cite this

Plater, M. J., Harrison, W. T. A., & Rzepa, H. S. (2015). Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative. Journal of Chemical Research, 39(12), 711-718. https://doi.org/10.3184/174751915X14474318419130

Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate : the first crystal structures of a mauveine chromophore and a synthetic derivative. / Plater, M. John ; Harrison, William T. A.; Rzepa, Henry S. .

In: Journal of Chemical Research, Vol. 39, No. 12, 01.12.2015, p. 711-718.

Research output: Contribution to journal › Article › peer-review

Plater, MJ , Harrison, WTA & Rzepa, HS 2015, 'Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative', Journal of Chemical Research, vol. 39, no. 12, pp. 711-718. https://doi.org/10.3184/174751915X14474318419130

@article{d2ddb0efb3b94422aa8225573646fcbf,

title = "Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative",

abstract = "Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.",

keywords = "aniline, mauve, mauveine, N-phenyl-p-phenylediamine, William Henry Perkin",

author = "Plater, {M. John} and Harrison, {William T. A.} and Rzepa, {Henry S.}",

note = "We thank the EPSRC National Mass Spectrometry Service Centre (University of Swansea) for measuring mass spectra and the EPSRC National Crystallography Service Centre (University of Southampton) for collecting the diffraction data.",

year = "2015",

month = dec,

day = "1",

doi = "10.3184/174751915X14474318419130",

language = "English",

volume = "39",

pages = "711--718",

journal = "Journal of Chemical Research",

issn = "0308-2342",

publisher = "Science Reviews Ltd",

number = "12",

}

TY - JOUR

T1 - Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate

T2 - the first crystal structures of a mauveine chromophore and a synthetic derivative

AU - Plater, M. John

AU - Harrison, William T. A.

AU - Rzepa, Henry S.

N1 - We thank the EPSRC National Mass Spectrometry Service Centre (University of Swansea) for measuring mass spectra and the EPSRC National Crystallography Service Centre (University of Southampton) for collecting the diffraction data.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.

AB - Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.

KW - aniline

KW - mauve

KW - mauveine

KW - N-phenyl-p-phenylediamine

KW - William Henry Perkin

U2 - 10.3184/174751915X14474318419130

DO - 10.3184/174751915X14474318419130

M3 - Article

VL - 39

SP - 711

EP - 718

JO - Journal of Chemical Research

JF - Journal of Chemical Research

SN - 0308-2342

IS - 12

ER -

Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative

Abstract

Keywords

Access to Document

Michael Plater

Cite this