Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative

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Abstract

Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.
Original languageEnglish
Pages (from-to)711-718
Number of pages8
JournalJournal of Chemical Research
Volume39
Issue number12
Early online date1 Dec 2015
DOIs
Publication statusPublished - 1 Dec 2015

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Chromophores
Ethanol
Crystal structure
Derivatives
Density functional theory
picric acid

Keywords

  • aniline
  • mauve
  • mauveine
  • N-phenyl-p-phenylediamine
  • William Henry Perkin

Cite this

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title = "Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate: the first crystal structures of a mauveine chromophore and a synthetic derivative",
abstract = "Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.",
keywords = "aniline, mauve, mauveine, N-phenyl-p-phenylediamine, William Henry Perkin",
author = "Plater, {M. John} and Harrison, {William T. A.} and Rzepa, {Henry S.}",
note = "We thank the EPSRC National Mass Spectrometry Service Centre (University of Swansea) for measuring mass spectra and the EPSRC National Crystallography Service Centre (University of Southampton) for collecting the diffraction data.",
year = "2015",
month = "12",
day = "1",
doi = "10.3184/174751915X14474318419130",
language = "English",
volume = "39",
pages = "711--718",
journal = "Journal of Chemical Research",
issn = "0308-2342",
publisher = "Science Reviews Ltd",
number = "12",

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TY - JOUR

T1 - Syntheses and structures of pseudo-mauveine picrate and 3-phenylamino-5(2-methylphenyl)-7-amino-8-methylphenazinium picrate ethanol mono-solvate

T2 - the first crystal structures of a mauveine chromophore and a synthetic derivative

AU - Plater, M. John

AU - Harrison, William T. A.

AU - Rzepa, Henry S.

N1 - We thank the EPSRC National Mass Spectrometry Service Centre (University of Swansea) for measuring mass spectra and the EPSRC National Crystallography Service Centre (University of Southampton) for collecting the diffraction data.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.

AB - Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.

KW - aniline

KW - mauve

KW - mauveine

KW - N-phenyl-p-phenylediamine

KW - William Henry Perkin

U2 - 10.3184/174751915X14474318419130

DO - 10.3184/174751915X14474318419130

M3 - Article

VL - 39

SP - 711

EP - 718

JO - Journal of Chemical Research

JF - Journal of Chemical Research

SN - 0308-2342

IS - 12

ER -