Syntheses and structures of the open-framework phases (CH3NH3)(3)center dot Zn4O(AsO4)(3) and (CH3NH3)(3)center dot Zn4O(PO4)(3) related to the M3Zn4O(XO4)(3)center dot nH(2)O family

W T A Harrison, M L F Phillips, A V Chavez, T M Nenoff

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38 Citations (Scopus)

Abstract

The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional "OZn4" + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.

Original languageEnglish
Pages (from-to)3087-3092
Number of pages6
JournalJournal of Materials Chemistry
Volume9
Publication statusPublished - 1999

Keywords

  • ROOM-TEMPERATURE SYNTHESIS
  • REFINEMENT
  • ZEOLITE

Cite this

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title = "Syntheses and structures of the open-framework phases (CH3NH3)(3)center dot Zn4O(AsO4)(3) and (CH3NH3)(3)center dot Zn4O(PO4)(3) related to the M3Zn4O(XO4)(3)center dot nH(2)O family",
abstract = "The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional {"}OZn4{"} + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.",
keywords = "ROOM-TEMPERATURE SYNTHESIS, REFINEMENT, ZEOLITE",
author = "Harrison, {W T A} and Phillips, {M L F} and Chavez, {A V} and Nenoff, {T M}",
year = "1999",
language = "English",
volume = "9",
pages = "3087--3092",
journal = "Journal of Materials Chemistry",
issn = "0959-9428",
publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Syntheses and structures of the open-framework phases (CH3NH3)(3)center dot Zn4O(AsO4)(3) and (CH3NH3)(3)center dot Zn4O(PO4)(3) related to the M3Zn4O(XO4)(3)center dot nH(2)O family

AU - Harrison, W T A

AU - Phillips, M L F

AU - Chavez, A V

AU - Nenoff, T M

PY - 1999

Y1 - 1999

N2 - The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional "OZn4" + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.

AB - The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional "OZn4" + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.

KW - ROOM-TEMPERATURE SYNTHESIS

KW - REFINEMENT

KW - ZEOLITE

M3 - Article

VL - 9

SP - 3087

EP - 3092

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

SN - 0959-9428

ER -