Abstract
The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional "OZn4" + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.
Original language | English |
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Pages (from-to) | 3087-3092 |
Number of pages | 6 |
Journal | Journal of Materials Chemistry |
Volume | 9 |
Publication status | Published - 1999 |
Keywords
- ROOM-TEMPERATURE SYNTHESIS
- REFINEMENT
- ZEOLITE