Syntheses and structures of the open-framework phases (CH3NH3)(3)center dot Zn4O(AsO4)(3) and (CH3NH3)(3)center dot Zn4O(PO4)(3) related to the M3Zn4O(XO4)(3)center dot nH(2)O family

W T A Harrison, M L F Phillips, A V Chavez, T M Nenoff

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional "OZn4" + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.

Original languageEnglish
Pages (from-to)3087-3092
Number of pages6
JournalJournal of Materials Chemistry
Volume9
Publication statusPublished - 1999

Keywords

  • ROOM-TEMPERATURE SYNTHESIS
  • REFINEMENT
  • ZEOLITE

Cite this