Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate

Michael John Plater, M. R. S. J. Foreman, T. Gelbrich, M. B. Hursthouse

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase I of composition [Cu(Py2C6H12)(3)(NO3)(2)].2[Cu(Py2C6H12)(2)(H2O)(NO3)].2(NO3). EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu-2(Py2C6H12)(4)(H2O)(2)]. (NO3)(4). (Py2C6H12). (EtOH).2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)319-328
Number of pages9
JournalCrystal Engineering
Volume4
DOIs
Publication statusPublished - 2001

Keywords

  • supramolecular
  • crystal engineering
  • POLYMER
  • CHANNELS
  • 1,3-BIS(4-PYRIDYL)PROPANE
  • FRAMEWORK
  • CATIONS
  • LIGANDS
  • SOLIDS

Cite this

Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate. / Plater, Michael John; Foreman, M. R. S. J.; Gelbrich, T.; Hursthouse, M. B.

In: Crystal Engineering, Vol. 4, 2001, p. 319-328.

Research output: Contribution to journalArticle

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abstract = "Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase I of composition [Cu(Py2C6H12)(3)(NO3)(2)].2[Cu(Py2C6H12)(2)(H2O)(NO3)].2(NO3). EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu-2(Py2C6H12)(4)(H2O)(2)]. (NO3)(4). (Py2C6H12). (EtOH).2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent. (C) 2001 Elsevier Science Ltd. All rights reserved.",
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AU - Foreman, M. R. S. J.

AU - Gelbrich, T.

AU - Hursthouse, M. B.

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N2 - Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase I of composition [Cu(Py2C6H12)(3)(NO3)(2)].2[Cu(Py2C6H12)(2)(H2O)(NO3)].2(NO3). EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu-2(Py2C6H12)(4)(H2O)(2)]. (NO3)(4). (Py2C6H12). (EtOH).2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase I of composition [Cu(Py2C6H12)(3)(NO3)(2)].2[Cu(Py2C6H12)(2)(H2O)(NO3)].2(NO3). EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu-2(Py2C6H12)(4)(H2O)(2)]. (NO3)(4). (Py2C6H12). (EtOH).2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent. (C) 2001 Elsevier Science Ltd. All rights reserved.

KW - supramolecular

KW - crystal engineering

KW - POLYMER

KW - CHANNELS

KW - 1,3-BIS(4-PYRIDYL)PROPANE

KW - FRAMEWORK

KW - CATIONS

KW - LIGANDS

KW - SOLIDS

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