Synthesis and characterisation of infinite di- and tri-nuclear zinc co-ordination networks with flexible dipyridyl ligands

M J Plater, M R S Foreman, T Gelbrich, M B Hursthouse

Research output: Contribution to journalArticle

85 Citations (Scopus)

Abstract

Crystallisation of flexible dipyridyl ligands with either Zn(NO3)(2). 6H(2)O or Zn(ClO4)(2). 6H(2)O gave co-ordination networks of composition [Zn-3(OH)(3){(NC5H4)(2)C3H6}(3)][NO3](3). 8.67H(2)O 1 [(NC5H4)(2)C3H6=1,3-bis(4- pyridyl)propane]; [Zn-2(OH){(NC5H4)(2)C4H8}(3)][ClO4](3). H2O . EtOH 2 [(NC5H4)C4H8=1,4-bis(4-pyridyl)butane] and [Zn-2(OH){(NC5H4)(2)C7H14}(4)][ClO4](3). 0.5H(2)O 3 [(NC5H4)(2)C7H14=1,7-bis(4- pyridyl)heptane]. The compounds were characterised by X-ray single crystal diffraction studies. Compound 1 possesses a trinuclear Zn-3(OH)(3) 6-membered ring that acts as a template for the co-ordination framework. Both 2 and 3 possess dinuclear zinc sub-units (Zn2OH) that contain a bridging hydroxyl ion.

Original languageEnglish
Pages (from-to)1995-2000
Number of pages6
JournalJournal of the Chemical Society, Dalton Transactions
DOIs
Publication statusPublished - 2000

Keywords

  • METAL-ORGANIC FRAMEWORK
  • X-RAY-DIFFRACTION
  • M = CO
  • COORDINATION POLYMERS
  • CRYSTAL-STRUCTURE
  • BENZENE-1,3,5-TRICARBOXYLIC ACID
  • HYDROTHERMAL SYNTHESIS
  • PHOSPHOLIPASE-C
  • BACILLUS-CEREUS
  • POROUS SOLIDS

Cite this

Synthesis and characterisation of infinite di- and tri-nuclear zinc co-ordination networks with flexible dipyridyl ligands. / Plater, M J ; Foreman, M R S ; Gelbrich, T ; Hursthouse, M B .

In: Journal of the Chemical Society, Dalton Transactions, 2000, p. 1995-2000.

Research output: Contribution to journalArticle

@article{e78cd34b61b24b3d9e4dc2db0480cd88,
title = "Synthesis and characterisation of infinite di- and tri-nuclear zinc co-ordination networks with flexible dipyridyl ligands",
abstract = "Crystallisation of flexible dipyridyl ligands with either Zn(NO3)(2). 6H(2)O or Zn(ClO4)(2). 6H(2)O gave co-ordination networks of composition [Zn-3(OH)(3){(NC5H4)(2)C3H6}(3)][NO3](3). 8.67H(2)O 1 [(NC5H4)(2)C3H6=1,3-bis(4- pyridyl)propane]; [Zn-2(OH){(NC5H4)(2)C4H8}(3)][ClO4](3). H2O . EtOH 2 [(NC5H4)C4H8=1,4-bis(4-pyridyl)butane] and [Zn-2(OH){(NC5H4)(2)C7H14}(4)][ClO4](3). 0.5H(2)O 3 [(NC5H4)(2)C7H14=1,7-bis(4- pyridyl)heptane]. The compounds were characterised by X-ray single crystal diffraction studies. Compound 1 possesses a trinuclear Zn-3(OH)(3) 6-membered ring that acts as a template for the co-ordination framework. Both 2 and 3 possess dinuclear zinc sub-units (Zn2OH) that contain a bridging hydroxyl ion.",
keywords = "METAL-ORGANIC FRAMEWORK, X-RAY-DIFFRACTION, M = CO, COORDINATION POLYMERS, CRYSTAL-STRUCTURE, BENZENE-1,3,5-TRICARBOXYLIC ACID, HYDROTHERMAL SYNTHESIS, PHOSPHOLIPASE-C, BACILLUS-CEREUS, POROUS SOLIDS",
author = "Plater, {M J} and Foreman, {M R S} and T Gelbrich and Hursthouse, {M B}",
year = "2000",
doi = "10.1039/b000566p",
language = "English",
pages = "1995--2000",
journal = "Journal of the Chemical Society, Dalton Transactions",
issn = "1472-7773",

}

TY - JOUR

T1 - Synthesis and characterisation of infinite di- and tri-nuclear zinc co-ordination networks with flexible dipyridyl ligands

AU - Plater, M J

AU - Foreman, M R S

AU - Gelbrich, T

AU - Hursthouse, M B

PY - 2000

Y1 - 2000

N2 - Crystallisation of flexible dipyridyl ligands with either Zn(NO3)(2). 6H(2)O or Zn(ClO4)(2). 6H(2)O gave co-ordination networks of composition [Zn-3(OH)(3){(NC5H4)(2)C3H6}(3)][NO3](3). 8.67H(2)O 1 [(NC5H4)(2)C3H6=1,3-bis(4- pyridyl)propane]; [Zn-2(OH){(NC5H4)(2)C4H8}(3)][ClO4](3). H2O . EtOH 2 [(NC5H4)C4H8=1,4-bis(4-pyridyl)butane] and [Zn-2(OH){(NC5H4)(2)C7H14}(4)][ClO4](3). 0.5H(2)O 3 [(NC5H4)(2)C7H14=1,7-bis(4- pyridyl)heptane]. The compounds were characterised by X-ray single crystal diffraction studies. Compound 1 possesses a trinuclear Zn-3(OH)(3) 6-membered ring that acts as a template for the co-ordination framework. Both 2 and 3 possess dinuclear zinc sub-units (Zn2OH) that contain a bridging hydroxyl ion.

AB - Crystallisation of flexible dipyridyl ligands with either Zn(NO3)(2). 6H(2)O or Zn(ClO4)(2). 6H(2)O gave co-ordination networks of composition [Zn-3(OH)(3){(NC5H4)(2)C3H6}(3)][NO3](3). 8.67H(2)O 1 [(NC5H4)(2)C3H6=1,3-bis(4- pyridyl)propane]; [Zn-2(OH){(NC5H4)(2)C4H8}(3)][ClO4](3). H2O . EtOH 2 [(NC5H4)C4H8=1,4-bis(4-pyridyl)butane] and [Zn-2(OH){(NC5H4)(2)C7H14}(4)][ClO4](3). 0.5H(2)O 3 [(NC5H4)(2)C7H14=1,7-bis(4- pyridyl)heptane]. The compounds were characterised by X-ray single crystal diffraction studies. Compound 1 possesses a trinuclear Zn-3(OH)(3) 6-membered ring that acts as a template for the co-ordination framework. Both 2 and 3 possess dinuclear zinc sub-units (Zn2OH) that contain a bridging hydroxyl ion.

KW - METAL-ORGANIC FRAMEWORK

KW - X-RAY-DIFFRACTION

KW - M = CO

KW - COORDINATION POLYMERS

KW - CRYSTAL-STRUCTURE

KW - BENZENE-1,3,5-TRICARBOXYLIC ACID

KW - HYDROTHERMAL SYNTHESIS

KW - PHOSPHOLIPASE-C

KW - BACILLUS-CEREUS

KW - POROUS SOLIDS

U2 - 10.1039/b000566p

DO - 10.1039/b000566p

M3 - Article

SP - 1995

EP - 2000

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 1472-7773

ER -