Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)

M J Plater, M R S Foreman, J M S Skakle

Research output: Contribution to journalArticle

Abstract

The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.

Original languageEnglish
Pages (from-to)535-537
Number of pages3
JournalJournal of Chemical Crystallography
Volume30
Publication statusPublished - 2000

Keywords

  • manganese
  • thiocyanate
  • pyridazine
  • COMPLEXES
  • OXIDATION

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