Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)

M J Plater, M R S Foreman, J M S Skakle

Research output: Contribution to journalArticle

Abstract

The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.

Original languageEnglish
Pages (from-to)535-537
Number of pages3
JournalJournal of Chemical Crystallography
Volume30
Publication statusPublished - 2000

Keywords

  • manganese
  • thiocyanate
  • pyridazine
  • COMPLEXES
  • OXIDATION

Cite this

Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine). / Plater, M J ; Foreman, M R S ; Skakle, J M S .

In: Journal of Chemical Crystallography, Vol. 30, 2000, p. 535-537.

Research output: Contribution to journalArticle

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abstract = "The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.",
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T1 - Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)

AU - Plater, M J

AU - Foreman, M R S

AU - Skakle, J M S

PY - 2000

Y1 - 2000

N2 - The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.

AB - The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.

KW - manganese

KW - thiocyanate

KW - pyridazine

KW - COMPLEXES

KW - OXIDATION

M3 - Article

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EP - 537

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

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