Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)

M J  Plater; M R S  Foreman; J M S  Skakle

Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)

M J Plater, M R S Foreman, J M S Skakle

Research output: Contribution to journal › Article

Abstract

The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.

Original language	English
Pages (from-to)	535-537
Number of pages	3
Journal	Journal of Chemical Crystallography
Volume	30
Publication status	Published - 2000

Keywords

manganese
thiocyanate
pyridazine
COMPLEXES
OXIDATION

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@article{ea231346b9174e599bcacb52b8191a4a,

title = "Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)",

abstract = "The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.",

keywords = "manganese, thiocyanate, pyridazine, COMPLEXES, OXIDATION",

author = "Plater, {M J} and Foreman, {M R S} and Skakle, {J M S}",

year = "2000",

language = "English",

volume = "30",

pages = "535--537",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer New York",

}

TY - JOUR

T1 - Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)

AU - Plater, M J

AU - Foreman, M R S

AU - Skakle, J M S

PY - 2000

Y1 - 2000

N2 - The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.

AB - The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Angstrom, b = 13.4312(7) Angstrom, c = 18.8992(9) Angstrom, V = 3284.1(3) Angstrom (3), and Z = 8.

KW - manganese

KW - thiocyanate

KW - pyridazine

KW - COMPLEXES

KW - OXIDATION

M3 - Article

SN - 1074-1542

VL - 30

SP - 535

EP - 537

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

ER -

Synthesis and crystal structure of [Mn(NCS)(2)L-2] (L=3,6-bis-(2-methylpyridyl)-1,2-pyridazine)

Abstract

Keywords

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