Synthesis and magnetic properties of a copper cube: [Cu4(OH)4(C16H18N2)4]4+ (ClO4)4 C3H6O [C16H18N2 = (E)-1,6-[di(pyridin-4-yl)hex-3-ene

M. John Plater; Amara Darr; Catriona Crawford; Craig Murray; Struan Simpson; William T. A. Harrison; Juan M. Clemente-Juan

doi:10.1002/open.201900260

Synthesis and magnetic properties of a copper cube: [Cu₄(OH)₄(C₁₆H₁₈N₂)₄]⁴⁺ (ClO₄)₄ C₃H₆O [C₁₆H₁₈N₂ = (E)-1,6-[di(pyridin-4-yl)hex-3-ene

M. John Plater^* (Corresponding Author), Amara Darr, Catriona Crawford, Craig Murray, Struan Simpson, William T. A. Harrison, Juan M. Clemente-Juan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Downloads (Pure)

Abstract

The synthesis of a Cu4(OH)4 cube which is coordinated by four molecules of the dipyridyl ligand 1,6‐[di(pyridin‐4‐yl)hex‐3‐ene] is reported. This compound has a trans double bond which restricts the conformational freedom of the ligand and favours coordination within a unique copper cube. The structure was solved by an X‐Ray single crystal structure determination and low temperature magnetic susceptibility measurements examined its magnetic properties. The cube classification corresponds to the type I classification of Mergehenn and Haase and the short/long distribution of Cu ⋅⋅⋅ Cu separations in the cube as defined by Ruiz. The magnetic susceptibility measurements show paramagnetic behaviour down to 50 K but below this the copper cube shows weak ferromagnetic exchange interactions. The low temperature magnetic susceptibility characteristics are examined in detail then modelled and compared to other similar Cu4O4 copper cubes.

Original language	English
Pages (from-to)	1204-1208
Number of pages	8
Journal	ChemistryOpen
Volume	8
Issue number	9
Early online date	11 Sept 2019
DOIs	https://doi.org/10.1002/open.201900260
Publication status	Published - Sept 2019

Bibliographical note

We are grateful to the National Mass Spectrometry Service Center for mass spectra and to the UK National Crystallography Service for data sets.

Supplementary

Figure S1-S4: IR and UV/Vis spectra of compound 1

Keywords

copper(II) perchlorate
hydroxyl ion
cube
(E)-1,6-[di(pyridin-4-yl)hex-3-ene]

Access to Document

10.1002/open.201900260Licence: CC BY-NC-ND

Synthesisand MagneticPropertiesof a CopperCube
©2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. https://creativecommons.org/licenses/by-nc-nd/4.0/
Final published version, 1.14 MBLicence: CC BY-NC-ND

Cite this

@article{6d8127a4d17640c0837af3ff10a1d0f0,

title = "Synthesis and magnetic properties of a copper cube: [Cu4(OH)4(C16H18N2)4]4+ (ClO4)4 C3H6O [C16H18N2 = (E)-1,6-[di(pyridin-4-yl)hex-3-ene",

abstract = "The synthesis of a Cu4(OH)4 cube which is coordinated by four molecules of the dipyridyl ligand 1,6‐[di(pyridin‐4‐yl)hex‐3‐ene] is reported. This compound has a trans double bond which restricts the conformational freedom of the ligand and favours coordination within a unique copper cube. The structure was solved by an X‐Ray single crystal structure determination and low temperature magnetic susceptibility measurements examined its magnetic properties. The cube classification corresponds to the type I classification of Mergehenn and Haase and the short/long distribution of Cu ⋅⋅⋅ Cu separations in the cube as defined by Ruiz. The magnetic susceptibility measurements show paramagnetic behaviour down to 50 K but below this the copper cube shows weak ferromagnetic exchange interactions. The low temperature magnetic susceptibility characteristics are examined in detail then modelled and compared to other similar Cu4O4 copper cubes.",

keywords = "copper(II) perchlorate, hydroxyl ion, cube, (E)-1,6-[di(pyridin-4-yl)hex-3-ene]",

author = "Plater, {M. John} and Amara Darr and Catriona Crawford and Craig Murray and Struan Simpson and Harrison, {William T. A.} and Clemente-Juan, {Juan M.}",

note = "We are grateful to the National Mass Spectrometry Service Center for mass spectra and to the UK National Crystallography Service for data sets. Supplementary Figure S1-S4: IR and UV/Vis spectra of compound 1",

year = "2019",

month = sep,

doi = "10.1002/open.201900260",

language = "English",

volume = "8",

pages = "1204--1208",

journal = "ChemistryOpen",

publisher = "John Wiley and Sons Inc.",

number = "9",

}

TY - JOUR

T1 - Synthesis and magnetic properties of a copper cube

T2 - [Cu4(OH)4(C16H18N2)4]4+ (ClO4)4 C3H6O [C16H18N2 = (E)-1,6-[di(pyridin-4-yl)hex-3-ene

AU - Plater, M. John

AU - Darr, Amara

AU - Crawford, Catriona

AU - Murray, Craig

AU - Simpson, Struan

AU - Harrison, William T. A.

AU - Clemente-Juan, Juan M.

N1 - We are grateful to the National Mass Spectrometry Service Center for mass spectra and to the UK National Crystallography Service for data sets. Supplementary Figure S1-S4: IR and UV/Vis spectra of compound 1

PY - 2019/9

Y1 - 2019/9

N2 - The synthesis of a Cu4(OH)4 cube which is coordinated by four molecules of the dipyridyl ligand 1,6‐[di(pyridin‐4‐yl)hex‐3‐ene] is reported. This compound has a trans double bond which restricts the conformational freedom of the ligand and favours coordination within a unique copper cube. The structure was solved by an X‐Ray single crystal structure determination and low temperature magnetic susceptibility measurements examined its magnetic properties. The cube classification corresponds to the type I classification of Mergehenn and Haase and the short/long distribution of Cu ⋅⋅⋅ Cu separations in the cube as defined by Ruiz. The magnetic susceptibility measurements show paramagnetic behaviour down to 50 K but below this the copper cube shows weak ferromagnetic exchange interactions. The low temperature magnetic susceptibility characteristics are examined in detail then modelled and compared to other similar Cu4O4 copper cubes.

AB - The synthesis of a Cu4(OH)4 cube which is coordinated by four molecules of the dipyridyl ligand 1,6‐[di(pyridin‐4‐yl)hex‐3‐ene] is reported. This compound has a trans double bond which restricts the conformational freedom of the ligand and favours coordination within a unique copper cube. The structure was solved by an X‐Ray single crystal structure determination and low temperature magnetic susceptibility measurements examined its magnetic properties. The cube classification corresponds to the type I classification of Mergehenn and Haase and the short/long distribution of Cu ⋅⋅⋅ Cu separations in the cube as defined by Ruiz. The magnetic susceptibility measurements show paramagnetic behaviour down to 50 K but below this the copper cube shows weak ferromagnetic exchange interactions. The low temperature magnetic susceptibility characteristics are examined in detail then modelled and compared to other similar Cu4O4 copper cubes.

KW - copper(II) perchlorate

KW - hydroxyl ion

KW - cube

KW - (E)-1,6-[di(pyridin-4-yl)hex-3-ene]

UR - http://www.mendeley.com/research/synthesis-magnetic-properties-copper-cube-cu-4-oh-4-c-16-h-18-n-2-4-4-clo-4-4-c-3-h-6-o-c-16-h-18-n

UR - http://www.scopus.com/inward/record.url?scp=85073194962&partnerID=8YFLogxK

U2 - 10.1002/open.201900260

DO - 10.1002/open.201900260

M3 - Article

C2 - 31523608

VL - 8

SP - 1204

EP - 1208

JO - ChemistryOpen

JF - ChemistryOpen

IS - 9

ER -

Synthesis and magnetic properties of a copper cube: [Cu₄(OH)₄(C₁₆H₁₈N₂)₄]⁴⁺ (ClO₄)₄ C₃H₆O [C₁₆H₁₈N₂ = (E)-1,6-[di(pyridin-4-yl)hex-3-ene

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Michael Plater

Cite this

Synthesis and magnetic properties of a copper cube: [Cu4(OH)4(C16H18N2)4]4+ (ClO4)4 C3H6O [C16H18N2 = (E)-1,6-[di(pyridin-4-yl)hex-3-ene

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Profiles

Michael Plater

Cite this

Synthesis and magnetic properties of a copper cube: [Cu₄(OH)₄(C₁₆H₁₈N₂)₄]⁴⁺ (ClO₄)₄ C₃H₆O [C₁₆H₁₈N₂ = (E)-1,6-[di(pyridin-4-yl)hex-3-ene