Synthesis and Structure of Cadmium Selenite Carbonate Hydroxide, Cd3[(SeO3)(CO3)(OH)2]

Magnus G. Johnston; William T A  Harrison

doi:10.1002/1521-3749(200209)628:9/10<2063::AID-ZAAC2063>3.0.CO;2-A

Synthesis and Structure of Cadmium Selenite Carbonate Hydroxide, Cd3[(SeO3)(CO3)(OH)2]

Magnus G. Johnston, William T A Harrison

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2 Citations (Scopus)

Abstract

The first selenite carbonate Cd-3(SeO3)(CO3)(OH)(2)] has been hydrothermally synthesised and characterised by single-crystal X-ray diffraction and IR spectroscopy. It is built up from a network of edge- and vertex-sharing pyramidal [SeO3](2-) groups, trigonal [CO3](2-) groups, distorted CdO6 octahedra and distorted CdO8 square anti-prisms. The CdO6 groups form infinite 'buckled' sheets in the ac plane with the SeO3 and CO3 groups cross-linking the sheets. The CdO8 polyhedra are wedged between adjacent sheets, sharing edges with both the selenite and carbonate groups. Crystal data: Cd-3(SeO3)(CO3)(OH)(2), M-r = 558.19, orthorhombic, Pnma (No. 62). a = 6.5820(3) Angstrom, b = 10.4485(5) Angstrom, c 10.3999(5) Angstrom, V = 715.22(6) Angstrom(3), Z = 4, R(F) = 0.0216, wR(F-2) = 0.0525.

Original language	English
Pages (from-to)	2063-2066
Number of pages	4
Journal	Zeitschrift für Anorganische und Allgemeine Chemie
Volume	628
Issue number	9-10
DOIs	https://doi.org/10.1002/1521-3749(200209)628:9/10<2063::AID-ZAAC2063>3.0.CO;2-A
Publication status	Published - Sep 2002

Keywords

selenium
cadmium
selenite
crystal structure

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10.1002/1521-3749(200209)628:9/10<2063::AID-ZAAC2063>3.0.CO;2-ALicence: Unspecified

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@article{a87e889f036c4a3ba4b85cff38951f29,

title = "Synthesis and Structure of Cadmium Selenite Carbonate Hydroxide, Cd3[(SeO3)(CO3)(OH)2]",

abstract = "The first selenite carbonate Cd-3(SeO3)(CO3)(OH)(2)] has been hydrothermally synthesised and characterised by single-crystal X-ray diffraction and IR spectroscopy. It is built up from a network of edge- and vertex-sharing pyramidal [SeO3](2-) groups, trigonal [CO3](2-) groups, distorted CdO6 octahedra and distorted CdO8 square anti-prisms. The CdO6 groups form infinite 'buckled' sheets in the ac plane with the SeO3 and CO3 groups cross-linking the sheets. The CdO8 polyhedra are wedged between adjacent sheets, sharing edges with both the selenite and carbonate groups. Crystal data: Cd-3(SeO3)(CO3)(OH)(2), M-r = 558.19, orthorhombic, Pnma (No. 62). a = 6.5820(3) Angstrom, b = 10.4485(5) Angstrom, c 10.3999(5) Angstrom, V = 715.22(6) Angstrom(3), Z = 4, R(F) = 0.0216, wR(F-2) = 0.0525.",

keywords = "selenium, cadmium, selenite, crystal structure",

author = "Johnston, {Magnus G.} and Harrison, {William T A}",

year = "2002",

month = sep,

doi = "10.1002/1521-3749(200209)628:9/10<2063::AID-ZAAC2063>3.0.CO;2-A",

language = "English",

volume = "628",

pages = "2063--2066",

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issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "9-10",

}

TY - JOUR

T1 - Synthesis and Structure of Cadmium Selenite Carbonate Hydroxide, Cd3[(SeO3)(CO3)(OH)2]

AU - Johnston, Magnus G.

AU - Harrison, William T A

PY - 2002/9

Y1 - 2002/9

N2 - The first selenite carbonate Cd-3(SeO3)(CO3)(OH)(2)] has been hydrothermally synthesised and characterised by single-crystal X-ray diffraction and IR spectroscopy. It is built up from a network of edge- and vertex-sharing pyramidal [SeO3](2-) groups, trigonal [CO3](2-) groups, distorted CdO6 octahedra and distorted CdO8 square anti-prisms. The CdO6 groups form infinite 'buckled' sheets in the ac plane with the SeO3 and CO3 groups cross-linking the sheets. The CdO8 polyhedra are wedged between adjacent sheets, sharing edges with both the selenite and carbonate groups. Crystal data: Cd-3(SeO3)(CO3)(OH)(2), M-r = 558.19, orthorhombic, Pnma (No. 62). a = 6.5820(3) Angstrom, b = 10.4485(5) Angstrom, c 10.3999(5) Angstrom, V = 715.22(6) Angstrom(3), Z = 4, R(F) = 0.0216, wR(F-2) = 0.0525.

AB - The first selenite carbonate Cd-3(SeO3)(CO3)(OH)(2)] has been hydrothermally synthesised and characterised by single-crystal X-ray diffraction and IR spectroscopy. It is built up from a network of edge- and vertex-sharing pyramidal [SeO3](2-) groups, trigonal [CO3](2-) groups, distorted CdO6 octahedra and distorted CdO8 square anti-prisms. The CdO6 groups form infinite 'buckled' sheets in the ac plane with the SeO3 and CO3 groups cross-linking the sheets. The CdO8 polyhedra are wedged between adjacent sheets, sharing edges with both the selenite and carbonate groups. Crystal data: Cd-3(SeO3)(CO3)(OH)(2), M-r = 558.19, orthorhombic, Pnma (No. 62). a = 6.5820(3) Angstrom, b = 10.4485(5) Angstrom, c 10.3999(5) Angstrom, V = 715.22(6) Angstrom(3), Z = 4, R(F) = 0.0216, wR(F-2) = 0.0525.

KW - selenium

KW - cadmium

KW - selenite

KW - crystal structure

U2 - 10.1002/1521-3749(200209)628:9/10<2063::AID-ZAAC2063>3.0.CO;2-A

DO - 10.1002/1521-3749(200209)628:9/10<2063::AID-ZAAC2063>3.0.CO;2-A

M3 - Article

VL - 628

SP - 2063

EP - 2066

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 9-10

ER -

Synthesis and Structure of Cadmium Selenite Carbonate Hydroxide, Cd3[(SeO3)(CO3)(OH)2]

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