Synthesis and structure of C2-symmetric N-heterocyclic carbene complexes of palladium

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Abstract

The first 9- and 11-membered cis and trans C-2-symmetric benzimidazol-2-ylidene palladium(11) complexes based on a trans-2,2-dimethyl-1,3-dioxalane backbone were synthesised and the configuration of the complexes was elucidated via NMR and X-ray crystallography. (C) 2004 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)5703-5706
Number of pages3
JournalTetrahedron Letters
Volume45
DOIs
Publication statusPublished - 2004

Keywords

  • C-2-symmetric
  • carbene
  • benzimidazol-2-ylidene palladium(II) complexes
  • OLEFIN METATHESIS
  • RUTHENIUM CATALYSTS
  • METAL-COMPLEXES
  • LIGANDS

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