Synthesis, crystal structure and properties of trans-[Cu(sac)(2)(en)(2)] (sac = saccharinato and en = ethylenediamine)

Serkan Guney, Veysel T. Yilmaz, William Thomas Alexander Harrison

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The title complex trans-[Cu(sac)(2)(en)(2)] (sac = saccharinato, en ethylenediamine) has been obtained accidentally by the reaction of piperazine (ppz) with [Cu(sac)(2)(H2O)(4)] center dot 2H(2)O in butanol solution. During the reaction, ppz was presumably decomposed to produce en which then coordinated to copper(II) to yield the title complex. trans-[Cu(sac)(2)(en)(2)] has been characterized by elemental analysis, IR, UV- VIS, magnetic measurements and single crystal X-ray diffraction. The compound crystallizes in space group P (1) over bar ( No. 2) and it consists of neutral units linked by bi- and trifurcated N-H center dot center dot center dot O hydrogen bonds into chains which are further connected by aromatic pi-pi stacking interactions forming a three-dimensional supramolecular network. The copper( II) ion in [Cu(sac)(2)(en)(2)] sits on a inversion centre and is octahedrally coordinated by two neutral en and two anionic sac ligands. An elongated distorted octahedral geometry along the Cu - N-sac bonds is a consequence of the Jahn - Teller effect. The en ligand acts as a bidentate (N, N') chelating ligand, while sac is N-coordinated. IR and UV spectra and thermal analysis are in agreement with the crystal structure.

Original languageEnglish
Pages (from-to)1123-1130
Number of pages8
JournalJournal of Coordination Chemistry
Volume59
Issue number10
Early online date21 Aug 2006
DOIs
Publication statusPublished - 2006

Keywords

  • ethylenediamine
  • saccharinato
  • copper(II) complex
  • crystal structure
  • metal complexes
  • coordination modes
  • ligand
  • copper(II)
  • versatile

Cite this

Synthesis, crystal structure and properties of trans-[Cu(sac)(2)(en)(2)] (sac = saccharinato and en = ethylenediamine). / Guney, Serkan; Yilmaz, Veysel T.; Harrison, William Thomas Alexander.

In: Journal of Coordination Chemistry, Vol. 59, No. 10, 2006, p. 1123-1130.

Research output: Contribution to journalArticle

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abstract = "The title complex trans-[Cu(sac)(2)(en)(2)] (sac = saccharinato, en ethylenediamine) has been obtained accidentally by the reaction of piperazine (ppz) with [Cu(sac)(2)(H2O)(4)] center dot 2H(2)O in butanol solution. During the reaction, ppz was presumably decomposed to produce en which then coordinated to copper(II) to yield the title complex. trans-[Cu(sac)(2)(en)(2)] has been characterized by elemental analysis, IR, UV- VIS, magnetic measurements and single crystal X-ray diffraction. The compound crystallizes in space group P (1) over bar ( No. 2) and it consists of neutral units linked by bi- and trifurcated N-H center dot center dot center dot O hydrogen bonds into chains which are further connected by aromatic pi-pi stacking interactions forming a three-dimensional supramolecular network. The copper( II) ion in [Cu(sac)(2)(en)(2)] sits on a inversion centre and is octahedrally coordinated by two neutral en and two anionic sac ligands. An elongated distorted octahedral geometry along the Cu - N-sac bonds is a consequence of the Jahn - Teller effect. The en ligand acts as a bidentate (N, N') chelating ligand, while sac is N-coordinated. IR and UV spectra and thermal analysis are in agreement with the crystal structure.",
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AU - Harrison, William Thomas Alexander

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N2 - The title complex trans-[Cu(sac)(2)(en)(2)] (sac = saccharinato, en ethylenediamine) has been obtained accidentally by the reaction of piperazine (ppz) with [Cu(sac)(2)(H2O)(4)] center dot 2H(2)O in butanol solution. During the reaction, ppz was presumably decomposed to produce en which then coordinated to copper(II) to yield the title complex. trans-[Cu(sac)(2)(en)(2)] has been characterized by elemental analysis, IR, UV- VIS, magnetic measurements and single crystal X-ray diffraction. The compound crystallizes in space group P (1) over bar ( No. 2) and it consists of neutral units linked by bi- and trifurcated N-H center dot center dot center dot O hydrogen bonds into chains which are further connected by aromatic pi-pi stacking interactions forming a three-dimensional supramolecular network. The copper( II) ion in [Cu(sac)(2)(en)(2)] sits on a inversion centre and is octahedrally coordinated by two neutral en and two anionic sac ligands. An elongated distorted octahedral geometry along the Cu - N-sac bonds is a consequence of the Jahn - Teller effect. The en ligand acts as a bidentate (N, N') chelating ligand, while sac is N-coordinated. IR and UV spectra and thermal analysis are in agreement with the crystal structure.

AB - The title complex trans-[Cu(sac)(2)(en)(2)] (sac = saccharinato, en ethylenediamine) has been obtained accidentally by the reaction of piperazine (ppz) with [Cu(sac)(2)(H2O)(4)] center dot 2H(2)O in butanol solution. During the reaction, ppz was presumably decomposed to produce en which then coordinated to copper(II) to yield the title complex. trans-[Cu(sac)(2)(en)(2)] has been characterized by elemental analysis, IR, UV- VIS, magnetic measurements and single crystal X-ray diffraction. The compound crystallizes in space group P (1) over bar ( No. 2) and it consists of neutral units linked by bi- and trifurcated N-H center dot center dot center dot O hydrogen bonds into chains which are further connected by aromatic pi-pi stacking interactions forming a three-dimensional supramolecular network. The copper( II) ion in [Cu(sac)(2)(en)(2)] sits on a inversion centre and is octahedrally coordinated by two neutral en and two anionic sac ligands. An elongated distorted octahedral geometry along the Cu - N-sac bonds is a consequence of the Jahn - Teller effect. The en ligand acts as a bidentate (N, N') chelating ligand, while sac is N-coordinated. IR and UV spectra and thermal analysis are in agreement with the crystal structure.

KW - ethylenediamine

KW - saccharinato

KW - copper(II) complex

KW - crystal structure

KW - metal complexes

KW - coordination modes

KW - ligand

KW - copper(II)

KW - versatile

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