Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands

S Hamamci, V T Yilmaz, W T A Harrison

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Abstract

A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)191-195
Number of pages5
JournalJournal of Molecular Structure
Volume734
DOIs
Publication statusPublished - 2005

Keywords

  • silver(I)
  • saccharin
  • N-(2-hydroxyethyl)piperazine
  • one-dimensional polymer
  • COMPLEXES
  • NITRATE
  • <M(C7H4NO3S)2(H2O)4>.2H2O

Cite this

@article{24ada0db78dc4accb1e47f31f5ff5aa1,
title = "Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands",
abstract = "A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.",
keywords = "silver(I), saccharin, N-(2-hydroxyethyl)piperazine, one-dimensional polymer, COMPLEXES, NITRATE, <M(C7H4NO3S)2(H2O)4>.2H2O",
author = "S Hamamci and Yilmaz, {V T} and Harrison, {W T A}",
year = "2005",
doi = "10.1016/j.molstruc.2004.09.023",
language = "English",
volume = "734",
pages = "191--195",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier Science B. V.",

}

TY - JOUR

T1 - Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands

AU - Hamamci, S

AU - Yilmaz, V T

AU - Harrison, W T A

PY - 2005

Y1 - 2005

N2 - A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.

AB - A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.

KW - silver(I)

KW - saccharin

KW - N-(2-hydroxyethyl)piperazine

KW - one-dimensional polymer

KW - COMPLEXES

KW - NITRATE

KW - <M(C7H4NO3S)2(H2O)4>.2H2O

U2 - 10.1016/j.molstruc.2004.09.023

DO - 10.1016/j.molstruc.2004.09.023

M3 - Article

VL - 734

SP - 191

EP - 195

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -