Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands

S  Hamamci; V T  Yilmaz; W T A  Harrison

doi:10.1016/j.molstruc.2004.09.023

Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands

S Hamamci, V T Yilmaz, W T A Harrison

Chemistry

Research output: Contribution to journal › Article

38 Citations (Scopus)

Abstract

A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	191-195
Number of pages	5
Journal	Journal of Molecular Structure
Volume	734
DOIs	https://doi.org/10.1016/j.molstruc.2004.09.023
Publication status	Published - 2005

Keywords

silver(I)
saccharin
N-(2-hydroxyethyl)piperazine
one-dimensional polymer
COMPLEXES
NITRATE
<M(C7H4NO3S)2(H2O)4>.2H2O

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Hamamci, S., Yilmaz, V. T., & Harrison, W. T. A. (2005). Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands. Journal of Molecular Structure, 734, 191-195. https://doi.org/10.1016/j.molstruc.2004.09.023

Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands. / Hamamci, S ; Yilmaz, V T ; Harrison, W T A .
In: Journal of Molecular Structure, Vol. 734, 2005, p. 191-195.

Research output: Contribution to journal › Article

Hamamci, S, Yilmaz, VT & Harrison, WTA 2005, 'Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands', Journal of Molecular Structure, vol. 734, pp. 191-195. https://doi.org/10.1016/j.molstruc.2004.09.023

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title = "Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands",

abstract = "A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.",

keywords = "silver(I), saccharin, N-(2-hydroxyethyl)piperazine, one-dimensional polymer, COMPLEXES, NITRATE, <M(C7H4NO3S)2(H2O)4>.2H2O",

author = "S Hamamci and Yilmaz, {V T} and Harrison, {W T A}",

year = "2005",

doi = "10.1016/j.molstruc.2004.09.023",

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T1 - Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands

AU - Hamamci, S

AU - Yilmaz, V T

AU - Harrison, W T A

PY - 2005

Y1 - 2005

N2 - A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.

AB - A novel [Ag-2(mu-sac)(2)(mu-hep)(2)](n) [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) consists of dimeric [Ag-2(mu-sac)(2)] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag-2(mu-sac)(2)(mu-hep)(2)](n) contains two different silver(I) centerswith a Ag-Ag separation of 3.492(2) A. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(l) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. (C) 2004 Elsevier B.V. All rights reserved.

KW - silver(I)

KW - saccharin

KW - N-(2-hydroxyethyl)piperazine

KW - one-dimensional polymer

KW - COMPLEXES

KW - NITRATE

KW - <M(C7H4NO3S)2(H2O)4>.2H2O

U2 - 10.1016/j.molstruc.2004.09.023

DO - 10.1016/j.molstruc.2004.09.023

M3 - Article

SN - 0022-2860

VL - 734

SP - 191

EP - 195

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -