Synthesis of co-ordination networks selecting from either (R, R), (S, S) and (R, S)-1,4- or -1,3-bis[2-(4-pyridyl)-2-methylethyl] benzene and a discrete complex from 1,4-bis[2-(3-pyridyl)-2-methyl-cis-ethenyl)]benzene

Michael John Plater, Thomas Gelbrich, Michael B. Hursthouse, Ben M. De Silva

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Three distinct 2-D coordination networks with (4,4) topology where obtained from solutions containing a chiral ligand L and the appropriate metal salt, [CdL2(NO3)2](n)center dot H2O where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5), [CdL2(H2O)(2)](n)center dot L'center dot(H2O)(2)center dot(ClO4)(2) where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5) and [ML2(H2O)(2)](n)center dot L center dot(NO3)(2) where M = Co or Ni and L = (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl]benzene). These nets display different geometrical features including different modes of connection of L units by the four-connected metal centre. In addition, the infinite chain structure [CdL2(NO3)(2)](n)center dot H2O where L = (R, S)-1,3-bis[2-(4-pyridyl)-2-methyl)-ethyl] benzene whose metal centres are also four-connected and the finite molecular structure [CuL2(NO3)(2)]center dot H2O with L = 1,4-bis[2-(3-pyridyl)-2-methyl-cis-ethenyl)]benzene) were obtained.

Original languageEnglish
Pages (from-to)895-903
Number of pages9
JournalCrystEngComm
Volume8
Issue number12
Early online date23 Oct 2006
DOIs
Publication statusPublished - Dec 2006

Keywords

  • flexible dipyridyl ligands
  • metal organic framework
  • cadmium salts
  • polymers
  • dimensions
  • tectonics
  • crystals

Cite this

@article{765b96984f6e473b83b0063d0e2410ba,
title = "Synthesis of co-ordination networks selecting from either (R, R), (S, S) and (R, S)-1,4- or -1,3-bis[2-(4-pyridyl)-2-methylethyl] benzene and a discrete complex from 1,4-bis[2-(3-pyridyl)-2-methyl-cis-ethenyl)]benzene",
abstract = "Three distinct 2-D coordination networks with (4,4) topology where obtained from solutions containing a chiral ligand L and the appropriate metal salt, [CdL2(NO3)2](n)center dot H2O where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5), [CdL2(H2O)(2)](n)center dot L'center dot(H2O)(2)center dot(ClO4)(2) where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5) and [ML2(H2O)(2)](n)center dot L center dot(NO3)(2) where M = Co or Ni and L = (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl]benzene). These nets display different geometrical features including different modes of connection of L units by the four-connected metal centre. In addition, the infinite chain structure [CdL2(NO3)(2)](n)center dot H2O where L = (R, S)-1,3-bis[2-(4-pyridyl)-2-methyl)-ethyl] benzene whose metal centres are also four-connected and the finite molecular structure [CuL2(NO3)(2)]center dot H2O with L = 1,4-bis[2-(3-pyridyl)-2-methyl-cis-ethenyl)]benzene) were obtained.",
keywords = "flexible dipyridyl ligands, metal organic framework, cadmium salts, polymers, dimensions, tectonics , crystals",
author = "Plater, {Michael John} and Thomas Gelbrich and Hursthouse, {Michael B.} and {De Silva}, {Ben M.}",
year = "2006",
month = "12",
doi = "10.1039/b609740e",
language = "English",
volume = "8",
pages = "895--903",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "12",

}

TY - JOUR

T1 - Synthesis of co-ordination networks selecting from either (R, R), (S, S) and (R, S)-1,4- or -1,3-bis[2-(4-pyridyl)-2-methylethyl] benzene and a discrete complex from 1,4-bis[2-(3-pyridyl)-2-methyl-cis-ethenyl)]benzene

AU - Plater, Michael John

AU - Gelbrich, Thomas

AU - Hursthouse, Michael B.

AU - De Silva, Ben M.

PY - 2006/12

Y1 - 2006/12

N2 - Three distinct 2-D coordination networks with (4,4) topology where obtained from solutions containing a chiral ligand L and the appropriate metal salt, [CdL2(NO3)2](n)center dot H2O where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5), [CdL2(H2O)(2)](n)center dot L'center dot(H2O)(2)center dot(ClO4)(2) where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5) and [ML2(H2O)(2)](n)center dot L center dot(NO3)(2) where M = Co or Ni and L = (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl]benzene). These nets display different geometrical features including different modes of connection of L units by the four-connected metal centre. In addition, the infinite chain structure [CdL2(NO3)(2)](n)center dot H2O where L = (R, S)-1,3-bis[2-(4-pyridyl)-2-methyl)-ethyl] benzene whose metal centres are also four-connected and the finite molecular structure [CuL2(NO3)(2)]center dot H2O with L = 1,4-bis[2-(3-pyridyl)-2-methyl-cis-ethenyl)]benzene) were obtained.

AB - Three distinct 2-D coordination networks with (4,4) topology where obtained from solutions containing a chiral ligand L and the appropriate metal salt, [CdL2(NO3)2](n)center dot H2O where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5), [CdL2(H2O)(2)](n)center dot L'center dot(H2O)(2)center dot(ClO4)(2) where L = (R, R)-, (S, S)- and (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl] benzene (0.25 : 0.25 : 0.5) and [ML2(H2O)(2)](n)center dot L center dot(NO3)(2) where M = Co or Ni and L = (R, S)-1,4-bis[2-(4-pyridyl)-2-methyl)ethyl]benzene). These nets display different geometrical features including different modes of connection of L units by the four-connected metal centre. In addition, the infinite chain structure [CdL2(NO3)(2)](n)center dot H2O where L = (R, S)-1,3-bis[2-(4-pyridyl)-2-methyl)-ethyl] benzene whose metal centres are also four-connected and the finite molecular structure [CuL2(NO3)(2)]center dot H2O with L = 1,4-bis[2-(3-pyridyl)-2-methyl-cis-ethenyl)]benzene) were obtained.

KW - flexible dipyridyl ligands

KW - metal organic framework

KW - cadmium salts

KW - polymers

KW - dimensions

KW - tectonics

KW - crystals

U2 - 10.1039/b609740e

DO - 10.1039/b609740e

M3 - Article

VL - 8

SP - 895

EP - 903

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 12

ER -