Synthesis of [Mn(O2CCH2CH2CO2)(2,2 '-bipyridyl) (H2O)(2)](n)(H2O)-H-center dot

M J Plater, M R S Foreman, R A Howie

Research output: Contribution to journalArticle

Abstract

The title compound exists as a ID coordination polymer consisting of succinate anions, manganese cations and 2,2 ' -bipyridyl molecules. Twelve water molecules are present in the unit cell and are part of a hydrogen bonding system. Some of these waters are binding to manganese cations while others are only participating in hydrogen bonding. The structure has a monoclinic space group P2(1)/c with a = 8.2750(3) Angstrom, b = 11.5104(3) Angstrom and c = 16.9113(6) Angstrom, beta = 95.2727(16); V = 1603.96(9) Angstrom (3) and Z = 4.

Original languageEnglish
Pages (from-to)445-447
Number of pages3
JournalJournal of Chemical Crystallography
Volume30
Publication statusPublished - 2000

Keywords

  • coordination polymer
  • manganese
  • succinate
  • RAY

Cite this

Synthesis of [Mn(O2CCH2CH2CO2)(2,2 '-bipyridyl) (H2O)(2)](n)(H2O)-H-center dot. / Plater, M J ; Foreman, M R S ; Howie, R A .

In: Journal of Chemical Crystallography, Vol. 30, 2000, p. 445-447.

Research output: Contribution to journalArticle

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abstract = "The title compound exists as a ID coordination polymer consisting of succinate anions, manganese cations and 2,2 ' -bipyridyl molecules. Twelve water molecules are present in the unit cell and are part of a hydrogen bonding system. Some of these waters are binding to manganese cations while others are only participating in hydrogen bonding. The structure has a monoclinic space group P2(1)/c with a = 8.2750(3) Angstrom, b = 11.5104(3) Angstrom and c = 16.9113(6) Angstrom, beta = 95.2727(16); V = 1603.96(9) Angstrom (3) and Z = 4.",
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T1 - Synthesis of [Mn(O2CCH2CH2CO2)(2,2 '-bipyridyl) (H2O)(2)](n)(H2O)-H-center dot

AU - Plater, M J

AU - Foreman, M R S

AU - Howie, R A

PY - 2000

Y1 - 2000

N2 - The title compound exists as a ID coordination polymer consisting of succinate anions, manganese cations and 2,2 ' -bipyridyl molecules. Twelve water molecules are present in the unit cell and are part of a hydrogen bonding system. Some of these waters are binding to manganese cations while others are only participating in hydrogen bonding. The structure has a monoclinic space group P2(1)/c with a = 8.2750(3) Angstrom, b = 11.5104(3) Angstrom and c = 16.9113(6) Angstrom, beta = 95.2727(16); V = 1603.96(9) Angstrom (3) and Z = 4.

AB - The title compound exists as a ID coordination polymer consisting of succinate anions, manganese cations and 2,2 ' -bipyridyl molecules. Twelve water molecules are present in the unit cell and are part of a hydrogen bonding system. Some of these waters are binding to manganese cations while others are only participating in hydrogen bonding. The structure has a monoclinic space group P2(1)/c with a = 8.2750(3) Angstrom, b = 11.5104(3) Angstrom and c = 16.9113(6) Angstrom, beta = 95.2727(16); V = 1603.96(9) Angstrom (3) and Z = 4.

KW - coordination polymer

KW - manganese

KW - succinate

KW - RAY

M3 - Article

VL - 30

SP - 445

EP - 447

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

ER -