Tetraaquabis(biuret-kappa O-2 O ')-gadolinium(III) trichloride

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Abstract

In the title compound, [Gd(C2H5N3O2)(2)(H2O)(4)]Cl-3, which is isostrucutural with its yttrium analogue, the Gd3+ ion (site symmetry 2) is bonded to eight O atoms (arising from two O, O '-bidentate biuret molecules and four water molecules) in a distorted square-antiprismatic arrangement. A network of N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. One of the chloride ions has site symmetry 2.

Original languageEnglish
Article numberm620
Number of pages8
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number5
DOIs
Publication statusPublished - May 2008

Cite this

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title = "Tetraaquabis(biuret-kappa O-2 O ')-gadolinium(III) trichloride",
abstract = "In the title compound, [Gd(C2H5N3O2)(2)(H2O)(4)]Cl-3, which is isostrucutural with its yttrium analogue, the Gd3+ ion (site symmetry 2) is bonded to eight O atoms (arising from two O, O '-bidentate biuret molecules and four water molecules) in a distorted square-antiprismatic arrangement. A network of N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. One of the chloride ions has site symmetry 2.",
author = "Harrison, {William T. A.}",
year = "2008",
month = "5",
doi = "10.1107/S1600536808008660",
language = "English",
volume = "64",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "5",

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TY - JOUR

T1 - Tetraaquabis(biuret-kappa O-2 O ')-gadolinium(III) trichloride

AU - Harrison, William T. A.

PY - 2008/5

Y1 - 2008/5

N2 - In the title compound, [Gd(C2H5N3O2)(2)(H2O)(4)]Cl-3, which is isostrucutural with its yttrium analogue, the Gd3+ ion (site symmetry 2) is bonded to eight O atoms (arising from two O, O '-bidentate biuret molecules and four water molecules) in a distorted square-antiprismatic arrangement. A network of N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. One of the chloride ions has site symmetry 2.

AB - In the title compound, [Gd(C2H5N3O2)(2)(H2O)(4)]Cl-3, which is isostrucutural with its yttrium analogue, the Gd3+ ion (site symmetry 2) is bonded to eight O atoms (arising from two O, O '-bidentate biuret molecules and four water molecules) in a distorted square-antiprismatic arrangement. A network of N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. One of the chloride ions has site symmetry 2.

U2 - 10.1107/S1600536808008660

DO - 10.1107/S1600536808008660

M3 - Article

VL - 64

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 5

M1 - m620

ER -