Tetrahydrothiophene-1-oxide, TMSO, complexes of tin(IV) halides: crystal structures of SnCl4(TMSO)2[two polymorphs], SnBr4(TMSO)2 and Ph2SnCl2(TMSO)n (n=1 and 2)

R. Alan Howie; William T. A. Harrison; Geraldo M. de Lima; James L. Wardell; Solange M. S. V. Wardell

doi:10.1524/zkri.2010.1290

Tetrahydrothiophene-1-oxide, TMSO, complexes of tin(IV) halides: crystal structures of SnCl₄(TMSO)₂[two polymorphs], SnBr₄(TMSO)₂ and Ph₂SnCl₂(TMSO)n (n=1 and 2)

R. Alan Howie, William T. A. Harrison, Geraldo M. de Lima, James L. Wardell, Solange M. S. V. Wardell

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Crystal structures of five tin(IV) complexes containing the tetrahydrothiophene-1-oxide ligand, C4H8SO, TMSO, with Sn-O interactions, are described. They are trigonal bipyramidal Ph2SnCl2(TMSO), with TMSO and Cl in axial sites, and the octahedral complexes, Ph2SnCl2(TMSO)(2) and SnX4(TMSO)(2), where X = Br or Cl. In the octahedral complexes, the TMSO ligands are cis to one another and are trans to the halides. The SnCl4(TMSO)(2) complex has been obtained in two crystalline forms, one orthorhombic and isostructural with SnBr4(TMSO)(2), and the other triclinic. Strengths of the interactions of the tin halides with dimethyl sulfoxide, (DMSO), and TMSO ligands are compared.

Original language	English
Pages (from-to)	448-455
Number of pages	8
Journal	Zeitschrift für Kristallographie
Volume	225
Issue number	10
DOIs	https://doi.org/10.1524/zkri.2010.1290
Publication status	Published - 2010

Keywords

X-ray diffraction
Single crystal structure analysis
Tetrahydrothiophene-1-oxide
Tin(IV) complexes
Metal sulfide complexes
NN-dimethylformamide
Mossbauer
Dimethylsulfoxide
Spectra
Ligands

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10.1524/zkri.2010.1290

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Tetrahydrothiophene-1-oxide, TMSO, complexes of tin(IV) halides: crystal structures of SnCl₄(TMSO)₂[two polymorphs], SnBr₄(TMSO)₂ and Ph₂SnCl₂(TMSO)n (n=1 and 2). / Howie, R. Alan; Harrison, William T. A.; de Lima, Geraldo M. et al.
In: Zeitschrift für Kristallographie, Vol. 225, No. 10, 2010, p. 448-455.

Research output: Contribution to journal › Article › peer-review

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title = "Tetrahydrothiophene-1-oxide, TMSO, complexes of tin(IV) halides: crystal structures of SnCl4(TMSO)2[two polymorphs], SnBr4(TMSO)2 and Ph2SnCl2(TMSO)n (n=1 and 2)",

abstract = "Crystal structures of five tin(IV) complexes containing the tetrahydrothiophene-1-oxide ligand, C4H8SO, TMSO, with Sn-O interactions, are described. They are trigonal bipyramidal Ph2SnCl2(TMSO), with TMSO and Cl in axial sites, and the octahedral complexes, Ph2SnCl2(TMSO)(2) and SnX4(TMSO)(2), where X = Br or Cl. In the octahedral complexes, the TMSO ligands are cis to one another and are trans to the halides. The SnCl4(TMSO)(2) complex has been obtained in two crystalline forms, one orthorhombic and isostructural with SnBr4(TMSO)(2), and the other triclinic. Strengths of the interactions of the tin halides with dimethyl sulfoxide, (DMSO), and TMSO ligands are compared.",

keywords = "X-ray diffraction, Single crystal structure analysis, Tetrahydrothiophene-1-oxide, Tin(IV) complexes, Metal sulfide complexes, NN-dimethylformamide, Mossbauer, Dimethylsulfoxide, Spectra, Ligands",

author = "Howie, {R. Alan} and Harrison, {William T. A.} and {de Lima}, {Geraldo M.} and Wardell, {James L.} and Wardell, {Solange M. S. V.}",

year = "2010",

doi = "10.1524/zkri.2010.1290",

language = "English",

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AU - Howie, R. Alan

AU - Harrison, William T. A.

AU - de Lima, Geraldo M.

AU - Wardell, James L.

AU - Wardell, Solange M. S. V.

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N2 - Crystal structures of five tin(IV) complexes containing the tetrahydrothiophene-1-oxide ligand, C4H8SO, TMSO, with Sn-O interactions, are described. They are trigonal bipyramidal Ph2SnCl2(TMSO), with TMSO and Cl in axial sites, and the octahedral complexes, Ph2SnCl2(TMSO)(2) and SnX4(TMSO)(2), where X = Br or Cl. In the octahedral complexes, the TMSO ligands are cis to one another and are trans to the halides. The SnCl4(TMSO)(2) complex has been obtained in two crystalline forms, one orthorhombic and isostructural with SnBr4(TMSO)(2), and the other triclinic. Strengths of the interactions of the tin halides with dimethyl sulfoxide, (DMSO), and TMSO ligands are compared.

AB - Crystal structures of five tin(IV) complexes containing the tetrahydrothiophene-1-oxide ligand, C4H8SO, TMSO, with Sn-O interactions, are described. They are trigonal bipyramidal Ph2SnCl2(TMSO), with TMSO and Cl in axial sites, and the octahedral complexes, Ph2SnCl2(TMSO)(2) and SnX4(TMSO)(2), where X = Br or Cl. In the octahedral complexes, the TMSO ligands are cis to one another and are trans to the halides. The SnCl4(TMSO)(2) complex has been obtained in two crystalline forms, one orthorhombic and isostructural with SnBr4(TMSO)(2), and the other triclinic. Strengths of the interactions of the tin halides with dimethyl sulfoxide, (DMSO), and TMSO ligands are compared.

KW - X-ray diffraction

KW - Single crystal structure analysis

KW - Tetrahydrothiophene-1-oxide

KW - Tin(IV) complexes

KW - Metal sulfide complexes

KW - NN-dimethylformamide

KW - Mossbauer

KW - Dimethylsulfoxide

KW - Spectra

KW - Ligands

U2 - 10.1524/zkri.2010.1290

DO - 10.1524/zkri.2010.1290

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