Tetrakis(iodomethyl)stannane

R A  Howie; Jan Skakle; J L  Wardell

doi:10.1107/S160053680200274X

Tetrakis(iodomethyl)stannane

R A Howie, Jan Skakle, J L Wardell

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of the title compound, [Sn(CH2I)4], consists of Sn situated on a crystallographic fourfold rotatory inversion axis, with pendant iodomethyl groups whose atoms are in general positions. In the molecule, with overall crystallographically imposed S4 molecular symmetry, there is little, if any, distortion of the tetrahedral environment of Sn, but the bulk of I leads to opening up of the Sn-C-I angle to 112.4 (3)°.

Original language	English
Pages (from-to)	m105-m106
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	E58
DOIs	https://doi.org/10.1107/S160053680200274X
Publication status	Published - Mar 2002

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title = "Tetrakis(iodomethyl)stannane",

abstract = "The structure of the title compound, [Sn(CH2I)4], consists of Sn situated on a crystallographic fourfold rotatory inversion axis, with pendant iodomethyl groups whose atoms are in general positions. In the molecule, with overall crystallographically imposed S4 molecular symmetry, there is little, if any, distortion of the tetrahedral environment of Sn, but the bulk of I leads to opening up of the Sn-C-I angle to 112.4 (3)°. ",

author = "Howie, {R A} and Jan Skakle and Wardell, {J L}",

year = "2002",

month = mar,

doi = "10.1107/S160053680200274X",

language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Tetrakis(iodomethyl)stannane

AU - Howie, R A

AU - Skakle, Jan

AU - Wardell, J L

PY - 2002/3

Y1 - 2002/3

N2 - The structure of the title compound, [Sn(CH2I)4], consists of Sn situated on a crystallographic fourfold rotatory inversion axis, with pendant iodomethyl groups whose atoms are in general positions. In the molecule, with overall crystallographically imposed S4 molecular symmetry, there is little, if any, distortion of the tetrahedral environment of Sn, but the bulk of I leads to opening up of the Sn-C-I angle to 112.4 (3)°.

AB - The structure of the title compound, [Sn(CH2I)4], consists of Sn situated on a crystallographic fourfold rotatory inversion axis, with pendant iodomethyl groups whose atoms are in general positions. In the molecule, with overall crystallographically imposed S4 molecular symmetry, there is little, if any, distortion of the tetrahedral environment of Sn, but the bulk of I leads to opening up of the Sn-C-I angle to 112.4 (3)°.

U2 - 10.1107/S160053680200274X

DO - 10.1107/S160053680200274X

M3 - Article

SN - 1600-5368

VL - E58

SP - m105-m106

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

Tetrakis(iodomethyl)stannane

Abstract

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