Abstract
The title compound, trithallium trititanium oxide tris(phosphate) diphosphate, consists of a three-dimensional network of vertex-sharing TiO6, PO4 and P2O7 groups [d(av)(Ti-O) = 1.940(3) and d(av)(P-O) = 1.536(4)Angstrom]. Extra-framework Tl+ cations [d(av)(Tl-O) = 3.090(7)Angstrom] complete the structure, which is isostructural with M3Ti3O(PO4)(3)(P2O7) (M = K, Rb).
| Original language | English |
|---|---|
| Pages (from-to) | 1200-1203 |
| Number of pages | 4 |
| Journal | Acta Crystallographica Section C, Crystal Structure Communications |
| Volume | 55 |
| Publication status | Published - 1999 |