The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine

M.J. Plater; J.P. Sinclair; S. Aiken; T. Gelbrich; M.B. Hursthouse

doi:10.1016/j.tet.2004.03.059

The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine

M.J. Plater, J.P. Sinclair, S. Aiken, T. Gelbrich, M.B. Hursthouse

University of Southampton

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network. (C) 2004 Published by Elsevier Ltd.

Original language	English
Pages (from-to)	6385-6394
Number of pages	10
Journal	Tetrahedron
Volume	60
Issue number	30
DOIs	https://doi.org/10.1016/j.tet.2004.03.059
Publication status	Published - 19 Jul 2004

Keywords

2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine
cyanuric acid
hydrogen bonding
rosette motif
melamine
assemblies
polymers

Access to Document

10.1016/j.tet.2004.03.059

Cite this

@article{5b7e8abe175e4e13ae181303f962b277,

title = "The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine",

abstract = "Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network. (C) 2004 Published by Elsevier Ltd.",

keywords = "2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine, cyanuric acid, hydrogen bonding, rosette motif, melamine, assemblies, polymers",

author = "M.J. Plater and J.P. Sinclair and S. Aiken and T. Gelbrich and M.B. Hursthouse",

year = "2004",

month = jul,

day = "19",

doi = "10.1016/j.tet.2004.03.059",

language = "English",

volume = "60",

pages = "6385--6394",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "PERGAMON-ELSEVIER SCIENCE LTD",

number = "30",

}

TY - JOUR

T1 - The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine

AU - Plater, M.J.

AU - Sinclair, J.P.

AU - Aiken, S.

AU - Gelbrich, T.

AU - Hursthouse, M.B.

PY - 2004/7/19

Y1 - 2004/7/19

N2 - Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network. (C) 2004 Published by Elsevier Ltd.

AB - Five bis(isocyanuric) acid dimers have been prepared and characterised. The introduction of flexible alkyl chains was necessary to aid solubility. On mixing with N,N-bis(4-tert-butyphenyl)melamine in THF followed by slow evaporation, a viscous gel can form which is interpreted as evidence for the assembly of an infinite 2-D hydrogen bonded network. (C) 2004 Published by Elsevier Ltd.

KW - 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine

KW - cyanuric acid

KW - hydrogen bonding

KW - rosette motif

KW - melamine

KW - assemblies

KW - polymers

UR - http://www.scopus.com/inward/record.url?scp=3242790252&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2004.03.059

DO - 10.1016/j.tet.2004.03.059

M3 - Article

SN - 0040-4020

VL - 60

SP - 6385

EP - 6394

JO - Tetrahedron

JF - Tetrahedron

IS - 30

ER -

The CA.M lattice revisited. Gel formation from a linear bis-isocyanuric acid and 2-amino-4,6-bis-(4-tert-butylphenylamino)-1,3,5-triazine

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this