The crystal structure of a new oxide ion conductor NaBi3V2O10 and oxide ion conductivity in Pb2Bi2V2O10

D C Sinclair, E Marinou, J M S Skakle

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Abstract

Rietveld refinements using neutron diffraction data have been used to determine the crystal structure of the room temperature polymorph of a new oxide ion conductor, NaBi3V2O10. The cell is isostructural with Pb2Bi2V2O10 and the data refined in spacegroup P1 with cell parameters of a=7.0613(8), b=7.2086(8), c=5.5343(10) Angstrom, alpha=113.328(4), beta=84.4787(14) and gamma=112.249(3)degrees with an R value of 2.19%. The low symmetry of Pb2Bi2V2O10 and NaBi3V2O10 is attributed to structural distortions associated with electron lone pairs on Pb+II and Bi+III. Replacement of Pb+II by Bi+III and Na+I produces a structural phase transition to a higher symmetry polymorph in NaBi3V2O10 at ca. 575 degrees C. ac Impedance measurements show Pb2Bi2V2O10 to be a modest oxide ion conductor with conductivity of ca. 1 mS cm(-1) at 800 degrees C. As a result of the phase transition in NaBi3V2O10 its conductivity is ca. one order of magnitude greater than that of Pb2Bi2V2O10 at 600 degrees C.

Original languageEnglish
Pages (from-to)2617-2621
Number of pages5
JournalJournal of Materials Chemistry
Volume9
Publication statusPublished - 1999

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Cite this

The crystal structure of a new oxide ion conductor NaBi3V2O10 and oxide ion conductivity in Pb2Bi2V2O10. / Sinclair, D C ; Marinou, E ; Skakle, J M S .

In: Journal of Materials Chemistry, Vol. 9, 1999, p. 2617-2621.

Research output: Contribution to journalArticle

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abstract = "Rietveld refinements using neutron diffraction data have been used to determine the crystal structure of the room temperature polymorph of a new oxide ion conductor, NaBi3V2O10. The cell is isostructural with Pb2Bi2V2O10 and the data refined in spacegroup P1 with cell parameters of a=7.0613(8), b=7.2086(8), c=5.5343(10) Angstrom, alpha=113.328(4), beta=84.4787(14) and gamma=112.249(3)degrees with an R value of 2.19{\%}. The low symmetry of Pb2Bi2V2O10 and NaBi3V2O10 is attributed to structural distortions associated with electron lone pairs on Pb+II and Bi+III. Replacement of Pb+II by Bi+III and Na+I produces a structural phase transition to a higher symmetry polymorph in NaBi3V2O10 at ca. 575 degrees C. ac Impedance measurements show Pb2Bi2V2O10 to be a modest oxide ion conductor with conductivity of ca. 1 mS cm(-1) at 800 degrees C. As a result of the phase transition in NaBi3V2O10 its conductivity is ca. one order of magnitude greater than that of Pb2Bi2V2O10 at 600 degrees C.",
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AU - Skakle, J M S

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N2 - Rietveld refinements using neutron diffraction data have been used to determine the crystal structure of the room temperature polymorph of a new oxide ion conductor, NaBi3V2O10. The cell is isostructural with Pb2Bi2V2O10 and the data refined in spacegroup P1 with cell parameters of a=7.0613(8), b=7.2086(8), c=5.5343(10) Angstrom, alpha=113.328(4), beta=84.4787(14) and gamma=112.249(3)degrees with an R value of 2.19%. The low symmetry of Pb2Bi2V2O10 and NaBi3V2O10 is attributed to structural distortions associated with electron lone pairs on Pb+II and Bi+III. Replacement of Pb+II by Bi+III and Na+I produces a structural phase transition to a higher symmetry polymorph in NaBi3V2O10 at ca. 575 degrees C. ac Impedance measurements show Pb2Bi2V2O10 to be a modest oxide ion conductor with conductivity of ca. 1 mS cm(-1) at 800 degrees C. As a result of the phase transition in NaBi3V2O10 its conductivity is ca. one order of magnitude greater than that of Pb2Bi2V2O10 at 600 degrees C.

AB - Rietveld refinements using neutron diffraction data have been used to determine the crystal structure of the room temperature polymorph of a new oxide ion conductor, NaBi3V2O10. The cell is isostructural with Pb2Bi2V2O10 and the data refined in spacegroup P1 with cell parameters of a=7.0613(8), b=7.2086(8), c=5.5343(10) Angstrom, alpha=113.328(4), beta=84.4787(14) and gamma=112.249(3)degrees with an R value of 2.19%. The low symmetry of Pb2Bi2V2O10 and NaBi3V2O10 is attributed to structural distortions associated with electron lone pairs on Pb+II and Bi+III. Replacement of Pb+II by Bi+III and Na+I produces a structural phase transition to a higher symmetry polymorph in NaBi3V2O10 at ca. 575 degrees C. ac Impedance measurements show Pb2Bi2V2O10 to be a modest oxide ion conductor with conductivity of ca. 1 mS cm(-1) at 800 degrees C. As a result of the phase transition in NaBi3V2O10 its conductivity is ca. one order of magnitude greater than that of Pb2Bi2V2O10 at 600 degrees C.

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