The crystal structures of Li+ conducting phases Li0.5-3x RE0.5+xTiO3

RE=Pr,Nd, x≈0.05, from powder neutron diffraction data

R. I. Smith*, J. M.S. Skakle, G. C. Mather, M. Morales, A. R. West

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingChapter

8 Citations (Scopus)

Abstract

The crystal structures of the C polymorphs of the solid solutions Li0.5-3xRE0.5+xTiO3, RE=Pr,Nd, x∼0.05, have been refined by the Rietveld method from powder neutron diffraction data. At room temperature the C phases are orthorhombic and adopt the GdFeO3 structure type. The Li+ and RE cations share the A site, but with the Li+ displaced away from the ideal position.

Original languageEnglish
Title of host publicationEuropean Powder Diffraction 4
EditorsR.J. Cernik, R. Delhez, E.J. Mittemeijer
PublisherTrans Tech Publications Ltd
Pages701-704
Number of pages4
Volume228-231
EditionPart 2
ISBN (Print)978-0-87849-742-3
DOIs
Publication statusPublished - 31 Dec 1996

Publication series

NameMaterials Science Forum
PublisherTrans Tech Publications
Volume228-231
ISSN (Print)0255-5476

Fingerprint

Rietveld method
Neutron powder diffraction
Polymorphism
neutron diffraction
Cations
Solid solutions
solid solutions
Crystal structure
Positive ions
cations
conduction
crystal structure
room temperature
Temperature

Keywords

  • Lithium Ion Conductors
  • Neutron Diffraction
  • Perovskites
  • Rietveld Method

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Smith, R. I., Skakle, J. M. S., Mather, G. C., Morales, M., & West, A. R. (1996). The crystal structures of Li+ conducting phases Li0.5-3x RE0.5+xTiO3: RE=Pr,Nd, x≈0.05, from powder neutron diffraction data. In R. J. Cernik, R. Delhez, & E. J. Mittemeijer (Eds.), European Powder Diffraction 4 (Part 2 ed., Vol. 228-231, pp. 701-704). (Materials Science Forum; Vol. 228-231). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/MSF.228-231.701

The crystal structures of Li+ conducting phases Li0.5-3x RE0.5+xTiO3 : RE=Pr,Nd, x≈0.05, from powder neutron diffraction data. / Smith, R. I.; Skakle, J. M.S.; Mather, G. C.; Morales, M.; West, A. R.

European Powder Diffraction 4. ed. / R.J. Cernik; R. Delhez; E.J. Mittemeijer. Vol. 228-231 Part 2. ed. Trans Tech Publications Ltd, 1996. p. 701-704 (Materials Science Forum; Vol. 228-231).

Research output: Chapter in Book/Report/Conference proceedingChapter

Smith, RI, Skakle, JMS, Mather, GC, Morales, M & West, AR 1996, The crystal structures of Li+ conducting phases Li0.5-3x RE0.5+xTiO3: RE=Pr,Nd, x≈0.05, from powder neutron diffraction data. in RJ Cernik, R Delhez & EJ Mittemeijer (eds), European Powder Diffraction 4. Part 2 edn, vol. 228-231, Materials Science Forum, vol. 228-231, Trans Tech Publications Ltd, pp. 701-704. https://doi.org/10.4028/www.scientific.net/MSF.228-231.701
Smith RI, Skakle JMS, Mather GC, Morales M, West AR. The crystal structures of Li+ conducting phases Li0.5-3x RE0.5+xTiO3: RE=Pr,Nd, x≈0.05, from powder neutron diffraction data. In Cernik RJ, Delhez R, Mittemeijer EJ, editors, European Powder Diffraction 4. Part 2 ed. Vol. 228-231. Trans Tech Publications Ltd. 1996. p. 701-704. (Materials Science Forum). https://doi.org/10.4028/www.scientific.net/MSF.228-231.701
Smith, R. I. ; Skakle, J. M.S. ; Mather, G. C. ; Morales, M. ; West, A. R. / The crystal structures of Li+ conducting phases Li0.5-3x RE0.5+xTiO3 : RE=Pr,Nd, x≈0.05, from powder neutron diffraction data. European Powder Diffraction 4. editor / R.J. Cernik ; R. Delhez ; E.J. Mittemeijer. Vol. 228-231 Part 2. ed. Trans Tech Publications Ltd, 1996. pp. 701-704 (Materials Science Forum).
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