The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3)

Krishnan Srinivasan, Subbaiah Govindarajan, William Thomas Alexander Harrison

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)1117-1120
Number of pages4
JournalInorganic Chemistry Communications
Volume9
Issue number11
Early online date30 Jun 2006
DOIs
Publication statusPublished - Nov 2006

Keywords

  • ligand
  • sodium
  • crystal structure
  • molecular structure
  • derivatives
  • crystal

Cite this

The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3). / Srinivasan, Krishnan; Govindarajan, Subbaiah; Harrison, William Thomas Alexander.

In: Inorganic Chemistry Communications, Vol. 9, No. 11, 11.2006, p. 1117-1120.

Research output: Contribution to journalArticle

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abstract = "The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.",
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T1 - The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3)

AU - Srinivasan, Krishnan

AU - Govindarajan, Subbaiah

AU - Harrison, William Thomas Alexander

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N2 - The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.

AB - The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.

KW - ligand

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KW - crystal structure

KW - molecular structure

KW - derivatives

KW - crystal

U2 - 10.1016/j.inoche.2006.06.018

DO - 10.1016/j.inoche.2006.06.018

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