TY - JOUR
T1 - The preservation of fossil biomarkers during meteorite impact events
T2 - experimental evidence from biomarker-rich projectiles and target rocks
AU - Parnell, J.
AU - Bowden, S.
AU - Lindgren, P.
AU - Burchell, M.
AU - Milner, D.
AU - Price, M.
AU - Baldwin, E.C.
AU - Crawford, I. A.
PY - 2010/8/1
Y1 - 2010/8/1
N2 - A Devonian siltstone from Orkney, Scotland, shows survival of biomarkers in high-velocity impact experiments. The biomarkers were detected in ejecta fragments from experiments involving normal incidence of steel projectiles at 5-6 km s-1, and in projectile fragments from impact experiments into sand and water at 2-5 km s-1. The associated peak shock pressures were calculated to be in the range of 110-147 GPa for impacts of the steel projectiles into the siltstone target, and hydrocode simulations are used to show the variation of peak pressure with depth in the target and throughout the finite volume projectiles. Thermally sensitive biomarker ratios, including ratios of hopanoids and steranes, and the methylphenanthrene ratio, showed an increase in thermal maturity in the ejecta, and especially the projectile, fragments. Measurement of absolute concentrations of selected biomarkers indicates that changes in biomarker ratios reflect synthesis of new material rather than selective destruction. Their presence in ejecta and projectile fragments suggests that fossil biomarkers may survive hypervelocity impacts, and that experiments using biomarker-rich rock have high potential for testing survival of organic matter in a range of impact scenarios.
AB - A Devonian siltstone from Orkney, Scotland, shows survival of biomarkers in high-velocity impact experiments. The biomarkers were detected in ejecta fragments from experiments involving normal incidence of steel projectiles at 5-6 km s-1, and in projectile fragments from impact experiments into sand and water at 2-5 km s-1. The associated peak shock pressures were calculated to be in the range of 110-147 GPa for impacts of the steel projectiles into the siltstone target, and hydrocode simulations are used to show the variation of peak pressure with depth in the target and throughout the finite volume projectiles. Thermally sensitive biomarker ratios, including ratios of hopanoids and steranes, and the methylphenanthrene ratio, showed an increase in thermal maturity in the ejecta, and especially the projectile, fragments. Measurement of absolute concentrations of selected biomarkers indicates that changes in biomarker ratios reflect synthesis of new material rather than selective destruction. Their presence in ejecta and projectile fragments suggests that fossil biomarkers may survive hypervelocity impacts, and that experiments using biomarker-rich rock have high potential for testing survival of organic matter in a range of impact scenarios.
KW - polycyclic aromatic hydrocarbons
KW - carbonaceous Antarctic micrometeorites
KW - amino acids
KW - hypervelocity impacts
KW - organic molecules
KW - oblique impacts
KW - extraterrestrial delivery
KW - Martian meteorites
KW - cometary delivery
KW - shock pressures
UR - http://www.scopus.com/inward/record.url?scp=78649571346&partnerID=8YFLogxK
U2 - 10.1111/j.1945-5100.2010.01100.x
DO - 10.1111/j.1945-5100.2010.01100.x
M3 - Article
VL - 45
SP - 1340
EP - 1358
JO - Meteoritics & Planetary Sciences
JF - Meteoritics & Planetary Sciences
SN - 1086-9379
IS - 8
ER -