"The substituent doesn't matter": A robust hydrogen-bonding pattern in six substituted benzenesulfonyl asparagine derivatives

Islam Ullah Khan, Hafiz Mubashar-Ur-Rehman, Ejaz, William T. A. Harrison*

*Corresponding author for this work

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The syntheses and crystal structures of six substituted benzenesulfonyl-asparagine derivatives are reported. Despite showing three different unit cells and crystal symmetries, the molecular conformations and robust packing motifs are essentially the same in the six structures. In each case, [010] chains in which adjacent molecules are linked by three N-H· · · O hydrogen bonds are crosslinked by O-H· · · O hydrogen bonds to generate (001) sheets. Weak inter-sheet π-π interactions occur in some of the structures.

Original languageEnglish
Pages (from-to)53-60
Number of pages8
JournalZeitschrift für Kristallographie
Volume229
Issue number1
Early online date8 Jan 2014
DOIs
Publication statusPublished - Jan 2014

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Keywords

  • Asparagine
  • Hydrogen bonding
  • π-π stacking

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Inorganic Chemistry
  • Materials Science(all)

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