Thermal analysis characterization of the degradation of biodegradable starch blends in soil

A. Vallés Lluch, A Martinez-Felipe, A. Ribes-Greus, A Cadenato, X Ramis, J.M. Salla, J.M. Morancho

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Dynamic mechanical thermal analysis, differential scanning calorimetry (DSC), and thermogravimetric analysis were used to monitor the degradation of biodegradable blends in soil from vegetal sources consisting of dispersed thermoplastic starch and cellulosic derivatives. First, the viscoelastic behavior of this blend was studied. A prominent relaxation process at about 90°C and an overlapped small relaxation in the vicinity of 160°C were identified and characterized. The specific parameters were evaluated as a function of the soil burial time. Interesting changes in the mechanical relaxation spectra were observed. The intensity of the prominent peak at 90°C tended to decrease with degradation as a result of the reduction in the number of amylose chains in the starch. Second, thermogravimetric thermograms provided a register of the moisture content in the samples and the starch chain removal due to the degradation process. The nonisothermal kinetics of the decomposition processes were analyzed by means of Broido's integral method. The thermal stabilities of the nondegraded and degraded blends were estimated. The activation energies related to the correspondent reactions were calculated and evaluated as a function of the soil burial time. Furthermore, we used DSC as a complementary characterization technique to obtain information about the combined effect of moisture and the morphological changes that took place at molecular levels during the biodegradation process.
Original languageEnglish
Pages (from-to)358–371
Number of pages14
JournalJournal of Applied Polymer Science
Volume96
Issue number2
Early online date7 Feb 2005
DOIs
Publication statusPublished - 15 Apr 2005

Fingerprint

Starch
Thermoanalysis
Soils
Degradation
Differential scanning calorimetry
Moisture
Anelastic relaxation
Amylose
Relaxation processes
Biodegradation
Thermoplastics
Thermogravimetric analysis
Thermodynamic stability
Activation energy
Derivatives
Decomposition
Kinetics

Keywords

  • biodegradable
  • thermogravimetric analysis (TGA)
  • mechanical properties
  • differential scanning calorimetry (DSC)

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

Cite this

Vallés Lluch, A., Martinez-Felipe, A., Ribes-Greus, A., Cadenato, A., Ramis, X., Salla, J. M., & Morancho, J. M. (2005). Thermal analysis characterization of the degradation of biodegradable starch blends in soil. Journal of Applied Polymer Science, 96(2), 358–371. https://doi.org/10.1002/app.21428

Thermal analysis characterization of the degradation of biodegradable starch blends in soil. / Vallés Lluch, A.; Martinez-Felipe, A; Ribes-Greus, A.; Cadenato, A; Ramis, X; Salla, J.M.; Morancho, J.M.

In: Journal of Applied Polymer Science, Vol. 96, No. 2, 15.04.2005, p. 358–371.

Research output: Contribution to journalArticle

Vallés Lluch, A, Martinez-Felipe, A, Ribes-Greus, A, Cadenato, A, Ramis, X, Salla, JM & Morancho, JM 2005, 'Thermal analysis characterization of the degradation of biodegradable starch blends in soil', Journal of Applied Polymer Science, vol. 96, no. 2, pp. 358–371. https://doi.org/10.1002/app.21428
Vallés Lluch, A. ; Martinez-Felipe, A ; Ribes-Greus, A. ; Cadenato, A ; Ramis, X ; Salla, J.M. ; Morancho, J.M. / Thermal analysis characterization of the degradation of biodegradable starch blends in soil. In: Journal of Applied Polymer Science. 2005 ; Vol. 96, No. 2. pp. 358–371.
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