Thermodynamics of biofuels: Excess enthalpies for binary mixtures involving ethyl 1,1-dimethylethyl ether and hydrocarbons at different temperatures using a new flow calorimeter

Jose J. Segovia, M. Carmen Martin, David Vega-Maza, Cesar R. Chamorro, Miguel A. Villamañán

Research output: Contribution to journalArticle

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Abstract

Excess molar enthalpies for the binary systems: (ethyl 1,1-dimethylethyl ether + heptane); (ethyl 1,1-dimethylethyl ether + cyclohexane); (ethyl 1,1-dimethylethyl ether + toluene); (cyclohexane + toluene), and (toluene + heptane) have been measured at T = (298.15 and 313.15) K using a new isothermal flow calorimeter developed in the laboratory. The technique was previously checked by measuring test systems. The experimental results have been correlated with the Redlich–Kister polynomial equation. The mixing effects observed and the influence of the temperature are discussed.
Original languageEnglish
Pages (from-to)759-763
Number of pages5
JournalThe Journal of Chemical Thermodynamics
Volume41
Issue number6
Early online date14 Dec 2008
DOIs
Publication statusPublished - Jun 2009

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Biofuels
Toluene
Hydrocarbons
Binary mixtures
Calorimeters
Ether
binary mixtures
calorimeters
toluene
Heptanes
Enthalpy
Ethers
ethers
hydrocarbons
enthalpy
Heptane
Thermodynamics
Cyclohexane
heptanes
cyclohexane

Cite this

Thermodynamics of biofuels : Excess enthalpies for binary mixtures involving ethyl 1,1-dimethylethyl ether and hydrocarbons at different temperatures using a new flow calorimeter. / Segovia, Jose J.; Martin, M. Carmen; Vega-Maza, David; Chamorro, Cesar R.; Villamañán, Miguel A.

In: The Journal of Chemical Thermodynamics, Vol. 41, No. 6, 06.2009, p. 759-763.

Research output: Contribution to journalArticle

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