Thermodynamics of fuels with a biosynthetic component (III): Vapor–liquid equilibrium data for the ternary mixture ethyl 1,1-dimethylethyl ether, n-heptane and 1-hexene at T = 313.15 K

R M Villamañán, David Vega-Maza, C R Chamorro, M A Villamañán, J J Segovia

Research output: Contribution to journalArticle

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Abstract

Accurate vapor–liquid equilibria were measured for the ternary system ethyl 1,1-dimethylethyl ether + n-heptane + 1-hexene using an isothermal total pressure cell. The experimental data were well correlated using Wohl expansion and Wilson, NRTL and UNIQUAC models. The system shows a slight positive deviation from the ideality. A comparison with similar ternary systems containing other ethers is also discussed in the paper.
Original languageEnglish
Pages (from-to)12-16
Number of pages5
JournalFluid Phase Equilibria
Volume265
Issue number1-2
Early online date28 Dec 2007
DOIs
Publication statusPublished - 25 Mar 2008

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hexenes
Heptane
Ternary systems
heptanes
ternary systems
Ether
Ethers
ethers
Thermodynamics
thermodynamics
deviation
expansion
cells
n-heptane
1-hexene

Keywords

  • VLE data
  • ternary mixture
  • ethyl 1
  • 1-dimethylethyl ether (ETBE)
  • n-Heptane
  • 1-hexene

Cite this

Thermodynamics of fuels with a biosynthetic component (III) : Vapor–liquid equilibrium data for the ternary mixture ethyl 1,1-dimethylethyl ether, n-heptane and 1-hexene at T = 313.15 K. / Villamañán, R M; Vega-Maza, David; Chamorro, C R; Villamañán, M A; Segovia, J J.

In: Fluid Phase Equilibria, Vol. 265, No. 1-2, 25.03.2008, p. 12-16.

Research output: Contribution to journalArticle

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AU - Vega-Maza, David

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AU - Villamañán, M A

AU - Segovia, J J

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KW - 1-dimethylethyl ether (ETBE)

KW - n-Heptane

KW - 1-hexene

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