Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine

C Glidewell, J N Low, J M S Skakle, J L Wardell

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21 Citations (Scopus)

Abstract

In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.

Original languageEnglish
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume62
DOIs
Publication statusPublished - 2006

Cite this

@article{777f63c7762247bfbd182cf5443a74de,
title = "Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine",
abstract = "In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.",
author = "C Glidewell and Low, {J N} and Skakle, {J M S} and Wardell, {J L}",
year = "2006",
doi = "10.1107/S0108270105035766",
language = "English",
volume = "62",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2006

Y1 - 2006

N2 - In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.

AB - In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.

U2 - 10.1107/S0108270105035766

DO - 10.1107/S0108270105035766

M3 - Article

VL - 62

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -