Three isomeric N-(nitrophenyl)-succinimides: isolated molecules, hydrogen-bonded sheets and a hydrogen-bonded three-dimensional framework

C Glidewell, J N Low, J M S Skakle, J L Wardell

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Molecules of N-(2-nitrophenyl) succinimide, C10H8N2O4, are linked into sheets by a combination of C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. Molecules of N-(3-nitrophenyl) succinimide are linked into a three-dimensional framework by a combination of a two-centre C-H center dot center dot center dot O hydrogen bond and a three-centre C-H center dot center dot center dot(O)(2) hydrogen bond. Molecules of N-(4-nitrophenyl) succinimide which lie across twofold rotation axes in space group C2/c, participate in no direction-specific intermolecular interactions.

Original languageEnglish
Pages (from-to)o216-o220
Number of pages5
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume61
Issue number4
DOIs
Publication statusPublished - Apr 2005

Fingerprint

Succinimides
Hydrogen
Hydrogen bonds
Molecules
succinimide

Keywords

  • absolute-structure

Cite this

@article{b7b9c6c45dca4132896a3433db9ebae1,
title = "Three isomeric N-(nitrophenyl)-succinimides: isolated molecules, hydrogen-bonded sheets and a hydrogen-bonded three-dimensional framework",
abstract = "Molecules of N-(2-nitrophenyl) succinimide, C10H8N2O4, are linked into sheets by a combination of C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. Molecules of N-(3-nitrophenyl) succinimide are linked into a three-dimensional framework by a combination of a two-centre C-H center dot center dot center dot O hydrogen bond and a three-centre C-H center dot center dot center dot(O)(2) hydrogen bond. Molecules of N-(4-nitrophenyl) succinimide which lie across twofold rotation axes in space group C2/c, participate in no direction-specific intermolecular interactions.",
keywords = "absolute-structure",
author = "C Glidewell and Low, {J N} and Skakle, {J M S} and Wardell, {J L}",
year = "2005",
month = "4",
doi = "10.1107/S0108270105004798",
language = "English",
volume = "61",
pages = "o216--o220",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "4",

}

TY - JOUR

T1 - Three isomeric N-(nitrophenyl)-succinimides

T2 - isolated molecules, hydrogen-bonded sheets and a hydrogen-bonded three-dimensional framework

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2005/4

Y1 - 2005/4

N2 - Molecules of N-(2-nitrophenyl) succinimide, C10H8N2O4, are linked into sheets by a combination of C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. Molecules of N-(3-nitrophenyl) succinimide are linked into a three-dimensional framework by a combination of a two-centre C-H center dot center dot center dot O hydrogen bond and a three-centre C-H center dot center dot center dot(O)(2) hydrogen bond. Molecules of N-(4-nitrophenyl) succinimide which lie across twofold rotation axes in space group C2/c, participate in no direction-specific intermolecular interactions.

AB - Molecules of N-(2-nitrophenyl) succinimide, C10H8N2O4, are linked into sheets by a combination of C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. Molecules of N-(3-nitrophenyl) succinimide are linked into a three-dimensional framework by a combination of a two-centre C-H center dot center dot center dot O hydrogen bond and a three-centre C-H center dot center dot center dot(O)(2) hydrogen bond. Molecules of N-(4-nitrophenyl) succinimide which lie across twofold rotation axes in space group C2/c, participate in no direction-specific intermolecular interactions.

KW - absolute-structure

U2 - 10.1107/S0108270105004798

DO - 10.1107/S0108270105004798

M3 - Article

VL - 61

SP - o216-o220

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 4

ER -