trans-Bis(ethanolamine-N,O)bis-(saccharinato-N)copper(II)

V T Yilmaz, O Andac, Y Topcu, W T A Harrison

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

In the title complex, [Cu(C7H4NO3S)(2)(C2H7NO)(2)], the Cu-II centre lies on an inversion centre and exhibits octahedral coordination, with the two ethanolamine (Hea) and two saccharinate [sac; anionic 1,2-benzisothiazol-3(2H)-one 1,1-dioxide] ligands in a trans configuration. The bidentate Hea ligands bridge axial and equatorial positions and the sac anions occupy equatorial sites around the distorted octahedral copper(II) centre [Cu-O = 2.3263 (16), Cu-N-Hea = 1.9923 (16) and Cu-N-sac = 2.1776 (16) Angstrom].

Original languageEnglish
Pages (from-to)271-272
Number of pages2
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume57
Publication statusPublished - 2001

Keywords

  • SACCHARINATE DIHYDRATE
  • CRYSTAL-STRUCTURES

Cite this

trans-Bis(ethanolamine-N,O)bis-(saccharinato-N)copper(II). / Yilmaz, V T ; Andac, O ; Topcu, Y ; Harrison, W T A .

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 57, 2001, p. 271-272.

Research output: Contribution to journalArticle

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abstract = "In the title complex, [Cu(C7H4NO3S)(2)(C2H7NO)(2)], the Cu-II centre lies on an inversion centre and exhibits octahedral coordination, with the two ethanolamine (Hea) and two saccharinate [sac; anionic 1,2-benzisothiazol-3(2H)-one 1,1-dioxide] ligands in a trans configuration. The bidentate Hea ligands bridge axial and equatorial positions and the sac anions occupy equatorial sites around the distorted octahedral copper(II) centre [Cu-O = 2.3263 (16), Cu-N-Hea = 1.9923 (16) and Cu-N-sac = 2.1776 (16) Angstrom].",
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TY - JOUR

T1 - trans-Bis(ethanolamine-N,O)bis-(saccharinato-N)copper(II)

AU - Yilmaz, V T

AU - Andac, O

AU - Topcu, Y

AU - Harrison, W T A

PY - 2001

Y1 - 2001

N2 - In the title complex, [Cu(C7H4NO3S)(2)(C2H7NO)(2)], the Cu-II centre lies on an inversion centre and exhibits octahedral coordination, with the two ethanolamine (Hea) and two saccharinate [sac; anionic 1,2-benzisothiazol-3(2H)-one 1,1-dioxide] ligands in a trans configuration. The bidentate Hea ligands bridge axial and equatorial positions and the sac anions occupy equatorial sites around the distorted octahedral copper(II) centre [Cu-O = 2.3263 (16), Cu-N-Hea = 1.9923 (16) and Cu-N-sac = 2.1776 (16) Angstrom].

AB - In the title complex, [Cu(C7H4NO3S)(2)(C2H7NO)(2)], the Cu-II centre lies on an inversion centre and exhibits octahedral coordination, with the two ethanolamine (Hea) and two saccharinate [sac; anionic 1,2-benzisothiazol-3(2H)-one 1,1-dioxide] ligands in a trans configuration. The bidentate Hea ligands bridge axial and equatorial positions and the sac anions occupy equatorial sites around the distorted octahedral copper(II) centre [Cu-O = 2.3263 (16), Cu-N-Hea = 1.9923 (16) and Cu-N-sac = 2.1776 (16) Angstrom].

KW - SACCHARINATE DIHYDRATE

KW - CRYSTAL-STRUCTURES

M3 - Article

VL - 57

SP - 271

EP - 272

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -