TY - JOUR
T1 - Tricarbonyl-1,10-phenanthroline(triphenylphosphine)molybdenum(0)
AU - Muir, Kathleen J.
AU - McQuillan, Geoffrey P.
AU - Harrison, William T. A.
PY - 2007/10
Y1 - 2007/10
N2 - In the title compound, [Mo(CO)3(C18H15P)(C12H8N2)] or C33H23MoN2O3P, the carbonyl groups are attached to one face of the MoC3N2P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal structure, a short C-H center dot center dot center dot O interaction (H center dot center dot center dot O = 2.34 Å) may help to establish the packing.
AB - In the title compound, [Mo(CO)3(C18H15P)(C12H8N2)] or C33H23MoN2O3P, the carbonyl groups are attached to one face of the MoC3N2P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal structure, a short C-H center dot center dot center dot O interaction (H center dot center dot center dot O = 2.34 Å) may help to establish the packing.
U2 - 10.1107/S1600536807043176
DO - 10.1107/S1600536807043176
M3 - Article
SN - 1600-5368
VL - 63
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 10
M1 - m2492
ER -