Tricarbonyl-1,10-phenanthroline(triphenylphosphine)molybdenum(0)

Kathleen J. Muir, Geoffrey P. McQuillan, William T. A. Harrison

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, [Mo(CO)3(C18H15P)(C12H8N2)] or C33H23MoN2O3P, the carbonyl groups are attached to one face of the MoC3N2P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal structure, a short C-H center dot center dot center dot O interaction (H center dot center dot center dot O = 2.34 Å) may help to establish the packing.
Original languageEnglish
Article numberm2492
Number of pages11
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number10
DOIs
Publication statusPublished - Oct 2007

Cite this

Tricarbonyl-1,10-phenanthroline(triphenylphosphine)molybdenum(0). / Muir, Kathleen J.; McQuillan, Geoffrey P.; Harrison, William T. A.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 10, m2492, 10.2007.

Research output: Contribution to journalArticle

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AB - In the title compound, [Mo(CO)3(C18H15P)(C12H8N2)] or C33H23MoN2O3P, the carbonyl groups are attached to one face of the MoC3N2P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal structure, a short C-H center dot center dot center dot O interaction (H center dot center dot center dot O = 2.34 Å) may help to establish the packing.

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