Triethanolamine zinc phosphite, (C6H13NO3)Zn-2(HPO3): A templated network or a network of clusters?

J A Johnstone, W T A Harrison

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

(C6H13NO3)Zn-2(HPO3) (I) displays an extended hybrid organic/ inorganic structure in which the triethanolamine organic species acts as an anionic tetradentate ligand, rather than a typical protonated cationic template. Crystal data for I: M-r = 357.89, monoclinic, P2(1)/c (no. 14), a = 8.4216(4)Angstrom, b = 9.9262(5) Angstrom, c = 12.8494(6) Angstrom, beta = 91.824(1)degrees, V = 1073.6(1) Angstrom(3), Z = 4.

Original languageEnglish
Pages (from-to)4567-4569
Number of pages3
JournalInorganic Chemistry
Volume43
DOIs
Publication statusPublished - 2004

Keywords

  • CENTER-DOT ZN-3(HPO3)(4)
  • HYDROTHERMAL SYNTHESIS
  • STRUCTURAL-CHARACTERIZATION
  • 3-DIMENSIONAL STRUCTURES
  • ZINCOPHOSPHITES
  • CHANNELS
  • COMPLEX

Cite this

Triethanolamine zinc phosphite, (C6H13NO3)Zn-2(HPO3): A templated network or a network of clusters? / Johnstone, J A ; Harrison, W T A .

In: Inorganic Chemistry, Vol. 43, 2004, p. 4567-4569.

Research output: Contribution to journalArticle

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abstract = "(C6H13NO3)Zn-2(HPO3) (I) displays an extended hybrid organic/ inorganic structure in which the triethanolamine organic species acts as an anionic tetradentate ligand, rather than a typical protonated cationic template. Crystal data for I: M-r = 357.89, monoclinic, P2(1)/c (no. 14), a = 8.4216(4)Angstrom, b = 9.9262(5) Angstrom, c = 12.8494(6) Angstrom, beta = 91.824(1)degrees, V = 1073.6(1) Angstrom(3), Z = 4.",
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N2 - (C6H13NO3)Zn-2(HPO3) (I) displays an extended hybrid organic/ inorganic structure in which the triethanolamine organic species acts as an anionic tetradentate ligand, rather than a typical protonated cationic template. Crystal data for I: M-r = 357.89, monoclinic, P2(1)/c (no. 14), a = 8.4216(4)Angstrom, b = 9.9262(5) Angstrom, c = 12.8494(6) Angstrom, beta = 91.824(1)degrees, V = 1073.6(1) Angstrom(3), Z = 4.

AB - (C6H13NO3)Zn-2(HPO3) (I) displays an extended hybrid organic/ inorganic structure in which the triethanolamine organic species acts as an anionic tetradentate ligand, rather than a typical protonated cationic template. Crystal data for I: M-r = 357.89, monoclinic, P2(1)/c (no. 14), a = 8.4216(4)Angstrom, b = 9.9262(5) Angstrom, c = 12.8494(6) Angstrom, beta = 91.824(1)degrees, V = 1073.6(1) Angstrom(3), Z = 4.

KW - CENTER-DOT ZN-3(HPO3)(4)

KW - HYDROTHERMAL SYNTHESIS

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KW - 3-DIMENSIONAL STRUCTURES

KW - ZINCOPHOSPHITES

KW - CHANNELS

KW - COMPLEX

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