Triethanolammonium dihydrogenphosphate

S Demir, V T Yilmaz, W T A Harrison

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The structure of the title compound, [HN(C2H4OH)(3)](+).-H2PO4- or C6H16NO3+.H2PO4-, contains two distinct dihydrogenphosphate anions and two triethanolammonium cations in the asymmetric unit. The H2PO4 units are linked in a polymeric chain by strong P-OH...O-P hydrogen bonds along the [010] direction, while the (H2PO4)(-) and [HN(C2H4OH)(3)](+) ions are connected by O-H...O hydrogen bonds to yield sheet-like entities. The triethanolammonium cation shows a tripodal conformation and the ammonium H atom forms an intramolecular trifurcated hydrogen bond with the O atoms of the three ethanol groups.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
DOIs
Publication statusPublished - 2003

Keywords

  • PHOSPHATES

Cite this

Triethanolammonium dihydrogenphosphate. / Demir, S ; Yilmaz, V T ; Harrison, W T A .

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, 2003.

Research output: Contribution to journalArticle

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AU - Yilmaz, V T

AU - Harrison, W T A

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AB - The structure of the title compound, [HN(C2H4OH)(3)](+).-H2PO4- or C6H16NO3+.H2PO4-, contains two distinct dihydrogenphosphate anions and two triethanolammonium cations in the asymmetric unit. The H2PO4 units are linked in a polymeric chain by strong P-OH...O-P hydrogen bonds along the [010] direction, while the (H2PO4)(-) and [HN(C2H4OH)(3)](+) ions are connected by O-H...O hydrogen bonds to yield sheet-like entities. The triethanolammonium cation shows a tripodal conformation and the ammonium H atom forms an intramolecular trifurcated hydrogen bond with the O atoms of the three ethanol groups.

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JO - Acta Crystallographica Section E: Structure Reports Online

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