Tris[4-(4-nitrophenyl)-3-aza-3-butenyl]amine: p-stacked chains of hydrogen-bonded R22(26) dimers

C. Glidewell, Janet Mabel Scott Skakle, J. L. Wardell

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.

Original languageEnglish
Pages (from-to)o75-o77
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC61
Issue number2
DOIs
Publication statusPublished - 2005

Cite this

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title = "Tris[4-(4-nitrophenyl)-3-aza-3-butenyl]amine: p-stacked chains of hydrogen-bonded R22(26) dimers",
abstract = "In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.",
author = "C. Glidewell and Skakle, {Janet Mabel Scott} and Wardell, {J. L.}",
year = "2005",
doi = "10.1107/S0108270104033141",
language = "English",
volume = "C61",
pages = "o75--o77",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "2",

}

TY - JOUR

T1 - Tris[4-(4-nitrophenyl)-3-aza-3-butenyl]amine: p-stacked chains of hydrogen-bonded R22(26) dimers

AU - Glidewell, C.

AU - Skakle, Janet Mabel Scott

AU - Wardell, J. L.

PY - 2005

Y1 - 2005

N2 - In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.

AB - In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.

U2 - 10.1107/S0108270104033141

DO - 10.1107/S0108270104033141

M3 - Article

VL - C61

SP - o75-o77

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 2

ER -