Two zincophosphite frameworks templated by 1,4-diaminobenzene: syntheses and structures of C(6)N(2)H10 center dot Zn(HPO3)(2) and (C6N2H8)(0.5)center dot ZnHPO3

A Kirkpatrick, W T A Harrison

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Abstract

The solution-mediated syntheses and single crystal structures of (C6N2H10Zn)-Zn-.(HPO3)(2) (I) and (C6N2H8)(0.5)(ZnHPO3)-Zn-. (II) are reported. Slight variation of the synthesis conditions led to two quite different phases. I contains infinite chains of ZnO4 and HPO3 groups with the protonated organic moiety acting as a template and interacting with the chains by N-(HO)-O-... hydrogen bonds and possible C-(HO)-O-... interactions. In II, the neutral 1,4-diamino benzene molecule bonds to Zn (as a ligand) and an unusual composite, "pillared", structure results, with the organic species bridging 6(3) polyhedral sheets, although N-(HO)-O-... bonds are also present. Similarities and differences to other zinc phosphites and phosphates are briefly discussed for I and II. Crystal data: C6N2H10-Zn(HPO3)(2), M-r = 335.48, monoclinic, C2/c (No. 15), a = 17.2471 (14) Angstrom, b = 9.0720 (8) Angstrom, c = 7.6529 (6) Angstrom, beta = 103.752 (2)degrees, V = 1163.09 (7) Angstrom(3), Z = 4, R(F) = 0.038, wR(F-2) = 0.084. (C6N2H8)(0.5)(ZnHPO3)-Zn-., M-r = 199.42, orthorhombic, Pbca (No. 61), a = 8.0314 (16) Angstrom, b = 8.1299 (16) Angstrom, c = 18.830 (4) Angstrom, V = 1229.5 (4) Angstrom(3), Z = 8, R(F) = 0.026, wR(F-2) = 0.055. (C) 2004 Elsevier SAS. All rights reserved.

Original languageEnglish
Pages (from-to)593-598
Number of pages6
JournalSolid State Sciences
Volume6
DOIs
Publication statusPublished - 2004

Keywords

  • CENTER-DOT ZN-3(HPO3)(4)
  • HPO3 PSEUDO PYRAMIDS
  • HYDROTHERMAL SYNTHESIS
  • 3-DIMENSIONAL STRUCTURES
  • ZNO4 TETRAHEDRA
  • BUILT-UP
  • PHOSPHATES
  • PHOSPHITE
  • NETWORKS
  • SOLIDS

Cite this

@article{c368f2b14c6741b68bee48e8652f0d29,
title = "Two zincophosphite frameworks templated by 1,4-diaminobenzene: syntheses and structures of C(6)N(2)H10 center dot Zn(HPO3)(2) and (C6N2H8)(0.5)center dot ZnHPO3",
abstract = "The solution-mediated syntheses and single crystal structures of (C6N2H10Zn)-Zn-.(HPO3)(2) (I) and (C6N2H8)(0.5)(ZnHPO3)-Zn-. (II) are reported. Slight variation of the synthesis conditions led to two quite different phases. I contains infinite chains of ZnO4 and HPO3 groups with the protonated organic moiety acting as a template and interacting with the chains by N-(HO)-O-... hydrogen bonds and possible C-(HO)-O-... interactions. In II, the neutral 1,4-diamino benzene molecule bonds to Zn (as a ligand) and an unusual composite, {"}pillared{"}, structure results, with the organic species bridging 6(3) polyhedral sheets, although N-(HO)-O-... bonds are also present. Similarities and differences to other zinc phosphites and phosphates are briefly discussed for I and II. Crystal data: C6N2H10-Zn(HPO3)(2), M-r = 335.48, monoclinic, C2/c (No. 15), a = 17.2471 (14) Angstrom, b = 9.0720 (8) Angstrom, c = 7.6529 (6) Angstrom, beta = 103.752 (2)degrees, V = 1163.09 (7) Angstrom(3), Z = 4, R(F) = 0.038, wR(F-2) = 0.084. (C6N2H8)(0.5)(ZnHPO3)-Zn-., M-r = 199.42, orthorhombic, Pbca (No. 61), a = 8.0314 (16) Angstrom, b = 8.1299 (16) Angstrom, c = 18.830 (4) Angstrom, V = 1229.5 (4) Angstrom(3), Z = 8, R(F) = 0.026, wR(F-2) = 0.055. (C) 2004 Elsevier SAS. All rights reserved.",
keywords = "CENTER-DOT ZN-3(HPO3)(4), HPO3 PSEUDO PYRAMIDS, HYDROTHERMAL SYNTHESIS, 3-DIMENSIONAL STRUCTURES, ZNO4 TETRAHEDRA, BUILT-UP, PHOSPHATES, PHOSPHITE, NETWORKS, SOLIDS",
author = "A Kirkpatrick and Harrison, {W T A}",
year = "2004",
doi = "10.1016/j.solidstatesciences.2004.03.009",
language = "English",
volume = "6",
pages = "593--598",
journal = "Solid State Sciences",
issn = "1293-2558",
publisher = "Elsevier Masson SAS",

}

TY - JOUR

T1 - Two zincophosphite frameworks templated by 1,4-diaminobenzene: syntheses and structures of C(6)N(2)H10 center dot Zn(HPO3)(2) and (C6N2H8)(0.5)center dot ZnHPO3

AU - Kirkpatrick, A

AU - Harrison, W T A

PY - 2004

Y1 - 2004

N2 - The solution-mediated syntheses and single crystal structures of (C6N2H10Zn)-Zn-.(HPO3)(2) (I) and (C6N2H8)(0.5)(ZnHPO3)-Zn-. (II) are reported. Slight variation of the synthesis conditions led to two quite different phases. I contains infinite chains of ZnO4 and HPO3 groups with the protonated organic moiety acting as a template and interacting with the chains by N-(HO)-O-... hydrogen bonds and possible C-(HO)-O-... interactions. In II, the neutral 1,4-diamino benzene molecule bonds to Zn (as a ligand) and an unusual composite, "pillared", structure results, with the organic species bridging 6(3) polyhedral sheets, although N-(HO)-O-... bonds are also present. Similarities and differences to other zinc phosphites and phosphates are briefly discussed for I and II. Crystal data: C6N2H10-Zn(HPO3)(2), M-r = 335.48, monoclinic, C2/c (No. 15), a = 17.2471 (14) Angstrom, b = 9.0720 (8) Angstrom, c = 7.6529 (6) Angstrom, beta = 103.752 (2)degrees, V = 1163.09 (7) Angstrom(3), Z = 4, R(F) = 0.038, wR(F-2) = 0.084. (C6N2H8)(0.5)(ZnHPO3)-Zn-., M-r = 199.42, orthorhombic, Pbca (No. 61), a = 8.0314 (16) Angstrom, b = 8.1299 (16) Angstrom, c = 18.830 (4) Angstrom, V = 1229.5 (4) Angstrom(3), Z = 8, R(F) = 0.026, wR(F-2) = 0.055. (C) 2004 Elsevier SAS. All rights reserved.

AB - The solution-mediated syntheses and single crystal structures of (C6N2H10Zn)-Zn-.(HPO3)(2) (I) and (C6N2H8)(0.5)(ZnHPO3)-Zn-. (II) are reported. Slight variation of the synthesis conditions led to two quite different phases. I contains infinite chains of ZnO4 and HPO3 groups with the protonated organic moiety acting as a template and interacting with the chains by N-(HO)-O-... hydrogen bonds and possible C-(HO)-O-... interactions. In II, the neutral 1,4-diamino benzene molecule bonds to Zn (as a ligand) and an unusual composite, "pillared", structure results, with the organic species bridging 6(3) polyhedral sheets, although N-(HO)-O-... bonds are also present. Similarities and differences to other zinc phosphites and phosphates are briefly discussed for I and II. Crystal data: C6N2H10-Zn(HPO3)(2), M-r = 335.48, monoclinic, C2/c (No. 15), a = 17.2471 (14) Angstrom, b = 9.0720 (8) Angstrom, c = 7.6529 (6) Angstrom, beta = 103.752 (2)degrees, V = 1163.09 (7) Angstrom(3), Z = 4, R(F) = 0.038, wR(F-2) = 0.084. (C6N2H8)(0.5)(ZnHPO3)-Zn-., M-r = 199.42, orthorhombic, Pbca (No. 61), a = 8.0314 (16) Angstrom, b = 8.1299 (16) Angstrom, c = 18.830 (4) Angstrom, V = 1229.5 (4) Angstrom(3), Z = 8, R(F) = 0.026, wR(F-2) = 0.055. (C) 2004 Elsevier SAS. All rights reserved.

KW - CENTER-DOT ZN-3(HPO3)(4)

KW - HPO3 PSEUDO PYRAMIDS

KW - HYDROTHERMAL SYNTHESIS

KW - 3-DIMENSIONAL STRUCTURES

KW - ZNO4 TETRAHEDRA

KW - BUILT-UP

KW - PHOSPHATES

KW - PHOSPHITE

KW - NETWORKS

KW - SOLIDS

U2 - 10.1016/j.solidstatesciences.2004.03.009

DO - 10.1016/j.solidstatesciences.2004.03.009

M3 - Article

VL - 6

SP - 593

EP - 598

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

ER -