Vapor Liquid Equilibria of Binary Mixtures of 1-Butyl-3-methylimidazolium Triflate (C(4)mimTfO) and Molecular Solvents: n-Alkyl Alcohols and Water

Marcus Stuckenholz, Emanuel A. Crespo, Lourdes F. Vega, Pedro J. Carvalho, Joao A. P. Coutinho, Wolfram Schroeer, Johannes Kiefer, Bernd Rathke

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Isobaric vapor liquid equilibria (VLE) of binary mixtures of the ionic liquid (IL) 1-butyl-3-methylimidazolium trifluoromethanesulfonate (C(4)mimTfO) with either water or short chained n-alkyl alcohols (methanol, ethanol, propan-1-ol, and butan-1-ol) are described in this study. Two different microebulliometers and a classical VLE apparatus were compared and the VLEs were determined in the composition range 0.4

Original languageEnglish
Pages (from-to)6017-6032
Number of pages16
JournalJournal of Physical Chemistry B
Volume122
Issue number22
Early online date7 May 2018
DOIs
Publication statusPublished - 7 Jun 2018

Keywords

  • DIRECTIONAL ATTRACTIVE FORCES
  • EQUATION-OF-STATE
  • ACETONE PLUS METHANOL
  • TEMPERATURE IONIC LIQUIDS
  • ORGANIC OXYGEN COMPOUNDS
  • HIGH-PRESSURE SEPARATION
  • TERNARY-SYSTEM ETHANOL
  • SOFT-SAFT EQUATION
  • THERMODYNAMIC PROPERTIES
  • PHASE-BEHAVIOR

Cite this

Vapor Liquid Equilibria of Binary Mixtures of 1-Butyl-3-methylimidazolium Triflate (C(4)mimTfO) and Molecular Solvents : n-Alkyl Alcohols and Water. / Stuckenholz, Marcus; Crespo, Emanuel A.; Vega, Lourdes F.; Carvalho, Pedro J.; Coutinho, Joao A. P.; Schroeer, Wolfram; Kiefer, Johannes; Rathke, Bernd.

In: Journal of Physical Chemistry B, Vol. 122, No. 22, 07.06.2018, p. 6017-6032.

Research output: Contribution to journalArticle

Stuckenholz, M, Crespo, EA, Vega, LF, Carvalho, PJ, Coutinho, JAP, Schroeer, W, Kiefer, J & Rathke, B 2018, 'Vapor Liquid Equilibria of Binary Mixtures of 1-Butyl-3-methylimidazolium Triflate (C(4)mimTfO) and Molecular Solvents: n-Alkyl Alcohols and Water' Journal of Physical Chemistry B, vol. 122, no. 22, pp. 6017-6032. https://doi.org/10.1021/acs.jpcb.8b03278
Stuckenholz, Marcus ; Crespo, Emanuel A. ; Vega, Lourdes F. ; Carvalho, Pedro J. ; Coutinho, Joao A. P. ; Schroeer, Wolfram ; Kiefer, Johannes ; Rathke, Bernd. / Vapor Liquid Equilibria of Binary Mixtures of 1-Butyl-3-methylimidazolium Triflate (C(4)mimTfO) and Molecular Solvents : n-Alkyl Alcohols and Water. In: Journal of Physical Chemistry B. 2018 ; Vol. 122, No. 22. pp. 6017-6032.
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abstract = "Isobaric vapor liquid equilibria (VLE) of binary mixtures of the ionic liquid (IL) 1-butyl-3-methylimidazolium trifluoromethanesulfonate (C(4)mimTfO) with either water or short chained n-alkyl alcohols (methanol, ethanol, propan-1-ol, and butan-1-ol) are described in this study. Two different microebulliometers and a classical VLE apparatus were compared and the VLEs were determined in the composition range 0.4",
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AB - Isobaric vapor liquid equilibria (VLE) of binary mixtures of the ionic liquid (IL) 1-butyl-3-methylimidazolium trifluoromethanesulfonate (C(4)mimTfO) with either water or short chained n-alkyl alcohols (methanol, ethanol, propan-1-ol, and butan-1-ol) are described in this study. Two different microebulliometers and a classical VLE apparatus were compared and the VLEs were determined in the composition range 0.4

KW - DIRECTIONAL ATTRACTIVE FORCES

KW - EQUATION-OF-STATE

KW - ACETONE PLUS METHANOL

KW - TEMPERATURE IONIC LIQUIDS

KW - ORGANIC OXYGEN COMPOUNDS

KW - HIGH-PRESSURE SEPARATION

KW - TERNARY-SYSTEM ETHANOL

KW - SOFT-SAFT EQUATION

KW - THERMODYNAMIC PROPERTIES

KW - PHASE-BEHAVIOR

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