X-ray crystal structure of trans-bis(monoethanolamine) bis(saccharinato)nickel(II)

O Andac, Y Topcu, V T Yilmaz, W T A Harrison

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The crystal structure of trans-bis(monoethanolamine)bis(saccharinato)nickel(II), [Ni(C7H4NO3S)(2)(C2H7NO)(2)], has been determined from X-ray diffraction data. The metal complex is monoclinic, with a = 11.0555(5), b = 8.9103(4), c = 11.3890(5) Angstrom, beta = 105.0230(10)degrees, Z = 2, and space group P2(1)/c. The structure consists of individual molecules. Two monoethanolamine molecules and two saccharinate anions coordinate the nickel atom forming a. distorted octahedron. The monoethanolamine molecules act as a bidentate ligand and form five-membered trans chelate rings, which constitute the plane of the coordination octahedron, while two saccharinate ions behave as a monodentate ligand occupying the axial positions. Intermolecular hydrogen bonds link the molecules to form a three-dimensional infinite structure.

Original languageEnglish
Pages (from-to)767-771
Number of pages5
JournalJournal of Chemical Crystallography
Volume30
Publication statusPublished - 2000

Keywords

  • saccharin
  • monoethanolamine
  • nickel(II) complex
  • hydrogen bonding
  • crystal structure
  • NONCONVENTIONAL HYDROGEN-BONDS
  • DIVALENT METAL-IONS
  • THERMAL-PROPERTIES
  • SACCHARINATE COMPLEXES
  • BIOLOGICAL INTEREST
  • <M(C7H4NO3S)2(H2O)4>.2H2O

Cite this

X-ray crystal structure of trans-bis(monoethanolamine) bis(saccharinato)nickel(II). / Andac, O ; Topcu, Y ; Yilmaz, V T ; Harrison, W T A .

In: Journal of Chemical Crystallography, Vol. 30, 2000, p. 767-771.

Research output: Contribution to journalArticle

@article{7c9422066a0a461eb5c2cca6427ccb5e,
title = "X-ray crystal structure of trans-bis(monoethanolamine) bis(saccharinato)nickel(II)",
abstract = "The crystal structure of trans-bis(monoethanolamine)bis(saccharinato)nickel(II), [Ni(C7H4NO3S)(2)(C2H7NO)(2)], has been determined from X-ray diffraction data. The metal complex is monoclinic, with a = 11.0555(5), b = 8.9103(4), c = 11.3890(5) Angstrom, beta = 105.0230(10)degrees, Z = 2, and space group P2(1)/c. The structure consists of individual molecules. Two monoethanolamine molecules and two saccharinate anions coordinate the nickel atom forming a. distorted octahedron. The monoethanolamine molecules act as a bidentate ligand and form five-membered trans chelate rings, which constitute the plane of the coordination octahedron, while two saccharinate ions behave as a monodentate ligand occupying the axial positions. Intermolecular hydrogen bonds link the molecules to form a three-dimensional infinite structure.",
keywords = "saccharin, monoethanolamine, nickel(II) complex, hydrogen bonding, crystal structure, NONCONVENTIONAL HYDROGEN-BONDS, DIVALENT METAL-IONS, THERMAL-PROPERTIES, SACCHARINATE COMPLEXES, BIOLOGICAL INTEREST, <M(C7H4NO3S)2(H2O)4>.2H2O",
author = "O Andac and Y Topcu and Yilmaz, {V T} and Harrison, {W T A}",
year = "2000",
language = "English",
volume = "30",
pages = "767--771",
journal = "Journal of Chemical Crystallography",
issn = "1074-1542",
publisher = "Springer New York",

}

TY - JOUR

T1 - X-ray crystal structure of trans-bis(monoethanolamine) bis(saccharinato)nickel(II)

AU - Andac, O

AU - Topcu, Y

AU - Yilmaz, V T

AU - Harrison, W T A

PY - 2000

Y1 - 2000

N2 - The crystal structure of trans-bis(monoethanolamine)bis(saccharinato)nickel(II), [Ni(C7H4NO3S)(2)(C2H7NO)(2)], has been determined from X-ray diffraction data. The metal complex is monoclinic, with a = 11.0555(5), b = 8.9103(4), c = 11.3890(5) Angstrom, beta = 105.0230(10)degrees, Z = 2, and space group P2(1)/c. The structure consists of individual molecules. Two monoethanolamine molecules and two saccharinate anions coordinate the nickel atom forming a. distorted octahedron. The monoethanolamine molecules act as a bidentate ligand and form five-membered trans chelate rings, which constitute the plane of the coordination octahedron, while two saccharinate ions behave as a monodentate ligand occupying the axial positions. Intermolecular hydrogen bonds link the molecules to form a three-dimensional infinite structure.

AB - The crystal structure of trans-bis(monoethanolamine)bis(saccharinato)nickel(II), [Ni(C7H4NO3S)(2)(C2H7NO)(2)], has been determined from X-ray diffraction data. The metal complex is monoclinic, with a = 11.0555(5), b = 8.9103(4), c = 11.3890(5) Angstrom, beta = 105.0230(10)degrees, Z = 2, and space group P2(1)/c. The structure consists of individual molecules. Two monoethanolamine molecules and two saccharinate anions coordinate the nickel atom forming a. distorted octahedron. The monoethanolamine molecules act as a bidentate ligand and form five-membered trans chelate rings, which constitute the plane of the coordination octahedron, while two saccharinate ions behave as a monodentate ligand occupying the axial positions. Intermolecular hydrogen bonds link the molecules to form a three-dimensional infinite structure.

KW - saccharin

KW - monoethanolamine

KW - nickel(II) complex

KW - hydrogen bonding

KW - crystal structure

KW - NONCONVENTIONAL HYDROGEN-BONDS

KW - DIVALENT METAL-IONS

KW - THERMAL-PROPERTIES

KW - SACCHARINATE COMPLEXES

KW - BIOLOGICAL INTEREST

KW - <M(C7H4NO3S)2(H2O)4>.2H2O

M3 - Article

VL - 30

SP - 767

EP - 771

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

ER -