Tetrakis(µ-guanidinoacetic acid-k2O:O')bis[(nitrato-kO)copper(II)]

J. L. de Miranda; J. Felcman; J. L. Wardell; Janet Mabel Scott Skakle

doi:10.1107/S0108270102013227

Tetrakis(µ-guanidinoacetic acid-k₂O:O')bis[(nitrato-kO)copper(II)]

J. L. de Miranda, J. Felcman, J. L. Wardell, Janet Mabel Scott Skakle

Physics

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The title compound, [Cu-2(NO3)(2) (C3H7N3O2)(4)], forms a centrosymmetric dimer, with the two Cu2+ ions separated by 2.6525 (6) Angstrom. The asymmetric unit contains a Cu atom coordinated to two guanidinoacetic acid ligands (via one carboxylate O atom from each ligand) and to a nitrate group. The inversion centre in P (1) over bar generates the entire molecule, in which each Cu atom is coordinated to four carboxylate and to one nitrate O atom; ignoring the Cu-Cu separation, the geometry about each Cu atom is square pyramidal. The amino acid ligand is in the zwitterionic form. Strong N-H...O hydrogen bonds lead to a three-dimensional supramolecular structure, in which the N...O distances are in the range 2.931 (4)-3.278 (3) Angstrom, with N-H...O angles ranging from 128 to 170degrees.

Original language	English
Pages (from-to)	m471-m474
Number of pages	4
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	C58
DOIs	https://doi.org/10.1107/S0108270102013227
Publication status	Published - 2002

Keywords

Chronic-renal-failure
guanidinoacetic acid
magnetic-properties
molecular-structure
crystal-structure
Inborn error
metabolism
Complexes
deficiency
creatine

Access to Document

10.1107/S0108270102013227

Cite this

@article{e23de212fa3348f08f2c48284f75a09f,

title = "Tetrakis(µ-guanidinoacetic acid-k2O:O')bis[(nitrato-kO)copper(II)]",

abstract = "The title compound, [Cu-2(NO3)(2) (C3H7N3O2)(4)], forms a centrosymmetric dimer, with the two Cu2+ ions separated by 2.6525 (6) Angstrom. The asymmetric unit contains a Cu atom coordinated to two guanidinoacetic acid ligands (via one carboxylate O atom from each ligand) and to a nitrate group. The inversion centre in P (1) over bar generates the entire molecule, in which each Cu atom is coordinated to four carboxylate and to one nitrate O atom; ignoring the Cu-Cu separation, the geometry about each Cu atom is square pyramidal. The amino acid ligand is in the zwitterionic form. Strong N-H...O hydrogen bonds lead to a three-dimensional supramolecular structure, in which the N...O distances are in the range 2.931 (4)-3.278 (3) Angstrom, with N-H...O angles ranging from 128 to 170degrees.",

keywords = "Chronic-renal-failure, guanidinoacetic acid, magnetic-properties, molecular-structure, crystal-structure, Inborn error, metabolism, Complexes, deficiency, creatine",

author = "{de Miranda}, {J. L.} and J. Felcman and Wardell, {J. L.} and Skakle, {Janet Mabel Scott}",

year = "2002",

doi = "10.1107/S0108270102013227",

language = "English",

volume = "C58",

pages = "m471--m474",

journal = "Acta Crystallographica Section C, Crystal Structure Communications",

issn = "0108-2701",

publisher = "Wiley-Blackwell ",

}

TY - JOUR

T1 - Tetrakis(µ-guanidinoacetic acid-k2O:O')bis[(nitrato-kO)copper(II)]

AU - de Miranda, J. L.

AU - Felcman, J.

AU - Wardell, J. L.

AU - Skakle, Janet Mabel Scott

PY - 2002

Y1 - 2002

N2 - The title compound, [Cu-2(NO3)(2) (C3H7N3O2)(4)], forms a centrosymmetric dimer, with the two Cu2+ ions separated by 2.6525 (6) Angstrom. The asymmetric unit contains a Cu atom coordinated to two guanidinoacetic acid ligands (via one carboxylate O atom from each ligand) and to a nitrate group. The inversion centre in P (1) over bar generates the entire molecule, in which each Cu atom is coordinated to four carboxylate and to one nitrate O atom; ignoring the Cu-Cu separation, the geometry about each Cu atom is square pyramidal. The amino acid ligand is in the zwitterionic form. Strong N-H...O hydrogen bonds lead to a three-dimensional supramolecular structure, in which the N...O distances are in the range 2.931 (4)-3.278 (3) Angstrom, with N-H...O angles ranging from 128 to 170degrees.

AB - The title compound, [Cu-2(NO3)(2) (C3H7N3O2)(4)], forms a centrosymmetric dimer, with the two Cu2+ ions separated by 2.6525 (6) Angstrom. The asymmetric unit contains a Cu atom coordinated to two guanidinoacetic acid ligands (via one carboxylate O atom from each ligand) and to a nitrate group. The inversion centre in P (1) over bar generates the entire molecule, in which each Cu atom is coordinated to four carboxylate and to one nitrate O atom; ignoring the Cu-Cu separation, the geometry about each Cu atom is square pyramidal. The amino acid ligand is in the zwitterionic form. Strong N-H...O hydrogen bonds lead to a three-dimensional supramolecular structure, in which the N...O distances are in the range 2.931 (4)-3.278 (3) Angstrom, with N-H...O angles ranging from 128 to 170degrees.

KW - Chronic-renal-failure

KW - guanidinoacetic acid

KW - magnetic-properties

KW - molecular-structure

KW - crystal-structure

KW - Inborn error

KW - metabolism

KW - Complexes

KW - deficiency

KW - creatine

U2 - 10.1107/S0108270102013227

DO - 10.1107/S0108270102013227

M3 - Article

SN - 0108-2701

VL - C58

SP - m471-m474

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

ER -