1,4-Diazoniabicyclo-[2.2.2]octane tetraaquatetrachlorolanthanate(III) chloride

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound, (C6H14N2)[LaCl4(H2O)(4)]Cl, is built up from organic cations, [La(H2O)(4)Cl-4](-) complex anions and uncoordinated chloride ions. The previously unseen rare-earth-containing complex ion is irregular in shape. A network of O-HcCl and N-HcCl hydrogen bonds helps to establish the structure. Prominent among these are two well defined trifurcated N-Hc(Cl,Cl,Cl) inter-actions. The La atom, one Cl atom, two N atoms and two C atoms possess site symmetry m.

Original languageEnglish
Pages (from-to)m1255-m1257
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE62
Issue number6
DOIs
Publication statusPublished - Jun 2006

Keywords

  • M = LA
  • crystal structures
  • PR
  • GD
  • CE

Cite this

1,4-Diazoniabicyclo-[2.2.2]octane tetraaquatetrachlorolanthanate(III) chloride. / Ritchie, L K ; Harrison, William Thomas Alexander.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. E62, No. 6, 06.2006, p. m1255-m1257 .

Research output: Contribution to journalArticle

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abstract = "The title compound, (C6H14N2)[LaCl4(H2O)(4)]Cl, is built up from organic cations, [La(H2O)(4)Cl-4](-) complex anions and uncoordinated chloride ions. The previously unseen rare-earth-containing complex ion is irregular in shape. A network of O-HcCl and N-HcCl hydrogen bonds helps to establish the structure. Prominent among these are two well defined trifurcated N-Hc(Cl,Cl,Cl) inter-actions. The La atom, one Cl atom, two N atoms and two C atoms possess site symmetry m.",
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AU - Ritchie, L K

AU - Harrison, William Thomas Alexander

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N2 - The title compound, (C6H14N2)[LaCl4(H2O)(4)]Cl, is built up from organic cations, [La(H2O)(4)Cl-4](-) complex anions and uncoordinated chloride ions. The previously unseen rare-earth-containing complex ion is irregular in shape. A network of O-HcCl and N-HcCl hydrogen bonds helps to establish the structure. Prominent among these are two well defined trifurcated N-Hc(Cl,Cl,Cl) inter-actions. The La atom, one Cl atom, two N atoms and two C atoms possess site symmetry m.

AB - The title compound, (C6H14N2)[LaCl4(H2O)(4)]Cl, is built up from organic cations, [La(H2O)(4)Cl-4](-) complex anions and uncoordinated chloride ions. The previously unseen rare-earth-containing complex ion is irregular in shape. A network of O-HcCl and N-HcCl hydrogen bonds helps to establish the structure. Prominent among these are two well defined trifurcated N-Hc(Cl,Cl,Cl) inter-actions. The La atom, one Cl atom, two N atoms and two C atoms possess site symmetry m.

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KW - GD

KW - CE

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JO - Acta Crystallographica Section E: Structure Reports Online

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