1,4-Diazoniabicyclo-[2.2.2]octane tetraaquatetrachlorolanthanate(III) chloride

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Abstract

The title compound, (C6H14N2)[LaCl4(H2O)(4)]Cl, is built up from organic cations, [La(H2O)(4)Cl-4](-) complex anions and uncoordinated chloride ions. The previously unseen rare-earth-containing complex ion is irregular in shape. A network of O-HcCl and N-HcCl hydrogen bonds helps to establish the structure. Prominent among these are two well defined trifurcated N-Hc(Cl,Cl,Cl) inter-actions. The La atom, one Cl atom, two N atoms and two C atoms possess site symmetry m.

Original languageEnglish
Pages (from-to)m1255-m1257
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE62
Issue number6
DOIs
Publication statusPublished - Jun 2006

Keywords

  • M = LA
  • crystal structures
  • PR
  • GD
  • CE

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