1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate

C A  Bremner; W T A  Harrison

doi:10.1107/S1600536803011668

1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate

C A Bremner, W T A Harrison

Chemistry

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.

Original language	English
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
DOIs	https://doi.org/10.1107/S1600536803011668
Publication status	Published - 2003

Keywords

PHOSPHATE

Access to Document

10.1107/S1600536803011668

Cite this

@article{73d1ac57f7624a20aa2a89afa2da12be,

title = "1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate",

abstract = "The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.",

keywords = "PHOSPHATE",

author = "Bremner, {C A} and Harrison, {W T A}",

year = "2003",

doi = "10.1107/S1600536803011668",

language = "English",

volume = "59",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - 1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate

AU - Bremner, C A

AU - Harrison, W T A

PY - 2003

Y1 - 2003

N2 - The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.

AB - The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.

KW - PHOSPHATE

U2 - 10.1107/S1600536803011668

DO - 10.1107/S1600536803011668

M3 - Article

SN - 1600-5368

VL - 59

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate

Abstract

Keywords

Access to Document

Fingerprint

Cite this