1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate

C A Bremner, W T A Harrison

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.

Original languageEnglish
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
DOIs
Publication statusPublished - 2003

Keywords

  • PHOSPHATE

Cite this

1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate. / Bremner, C A ; Harrison, W T A .

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, 2003.

Research output: Contribution to journalArticle

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N2 - The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.

AB - The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.

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JO - Acta Crystallographica Section E: Structure Reports Online

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