2-{[2-(1-Methyl-2,2-dioxo-3,4-dihydro-1H-2λ6,1-benzothia- zin-4-yl-idene)hydrazin-1-yl-idene]methyl}phenol

Muhammad Shafiq*, William T.A. Harrison, Islam Ullah Khan, Iftikhar Hussain Bukhari, Tanveer Hussain Bokhari

*Corresponding author for this work

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, C16H15N3O 3S, the dihedral angle between the aromatic rings is 8.18 (11)° and the C=N - N=C torsion angle is 178.59 (14)°. The conformation of the thia-zine ring is an envelope, with the S atom displaced by 0.8157 (18) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.045 Å). An intramolecular O - H⋯N hydrogen bond closes an S(6) ring. In the crystal, weak C - H⋯O interactions link the molecules, with all three O atoms acting as acceptors.

Original languageEnglish
Article number02643
Number of pages7
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Early online dateSep 2012
DOIs
Publication statusPublished - Sep 2012

Fingerprint

Phenol
phenols
Phenols
Atoms
rings
atoms
Dihedral angle
Torsional stress
torsion
Conformations
dihedral angle
Hydrogen bonds
envelopes
hydrogen bonds
deviation
Crystals
Molecules
crystals
molecules
interactions

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

2-{[2-(1-Methyl-2,2-dioxo-3,4-dihydro-1H-2λ6,1-benzothia- zin-4-yl-idene)hydrazin-1-yl-idene]methyl}phenol. / Shafiq, Muhammad; Harrison, William T.A.; Khan, Islam Ullah; Bukhari, Iftikhar Hussain; Bokhari, Tanveer Hussain.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, 02643, 09.2012.

Research output: Contribution to journalArticle

@article{69f201fc902649029a7bc091459b05ef,
title = "2-{[2-(1-Methyl-2,2-dioxo-3,4-dihydro-1H-2λ6,1-benzothia- zin-4-yl-idene)hydrazin-1-yl-idene]methyl}phenol",
abstract = "In the title compound, C16H15N3O 3S, the dihedral angle between the aromatic rings is 8.18 (11)° and the C=N - N=C torsion angle is 178.59 (14)°. The conformation of the thia-zine ring is an envelope, with the S atom displaced by 0.8157 (18) {\AA} from the mean plane of the other five atoms (r.m.s. deviation = 0.045 {\AA}). An intramolecular O - H⋯N hydrogen bond closes an S(6) ring. In the crystal, weak C - H⋯O interactions link the molecules, with all three O atoms acting as acceptors.",
author = "Muhammad Shafiq and Harrison, {William T.A.} and Khan, {Islam Ullah} and Bukhari, {Iftikhar Hussain} and Bokhari, {Tanveer Hussain}",
year = "2012",
month = "9",
doi = "10.1107/S1600536812034101",
language = "English",
volume = "68",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - 2-{[2-(1-Methyl-2,2-dioxo-3,4-dihydro-1H-2λ6,1-benzothia- zin-4-yl-idene)hydrazin-1-yl-idene]methyl}phenol

AU - Shafiq, Muhammad

AU - Harrison, William T.A.

AU - Khan, Islam Ullah

AU - Bukhari, Iftikhar Hussain

AU - Bokhari, Tanveer Hussain

PY - 2012/9

Y1 - 2012/9

N2 - In the title compound, C16H15N3O 3S, the dihedral angle between the aromatic rings is 8.18 (11)° and the C=N - N=C torsion angle is 178.59 (14)°. The conformation of the thia-zine ring is an envelope, with the S atom displaced by 0.8157 (18) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.045 Å). An intramolecular O - H⋯N hydrogen bond closes an S(6) ring. In the crystal, weak C - H⋯O interactions link the molecules, with all three O atoms acting as acceptors.

AB - In the title compound, C16H15N3O 3S, the dihedral angle between the aromatic rings is 8.18 (11)° and the C=N - N=C torsion angle is 178.59 (14)°. The conformation of the thia-zine ring is an envelope, with the S atom displaced by 0.8157 (18) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.045 Å). An intramolecular O - H⋯N hydrogen bond closes an S(6) ring. In the crystal, weak C - H⋯O interactions link the molecules, with all three O atoms acting as acceptors.

UR - http://www.scopus.com/inward/record.url?scp=84865732943&partnerID=8YFLogxK

U2 - 10.1107/S1600536812034101

DO - 10.1107/S1600536812034101

M3 - Article

VL - 68

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

M1 - 02643

ER -