TY - JOUR
T1 - (2,2 '-bipyridyl)tricarbonyl(di-2-pyridylamine)molybdenum(0) revisited
AU - Muir, Kathleen J.
AU - McQuillan, Geoffrey P.
AU - Harrison, William T. A.
PY - 2007/12
Y1 - 2007/12
N2 - The previous structure report [Howie & McQuillan (1986). J. Chem. Soc. Dalton Trans. pp. 759-764] of the title compound, [Mo(C10H8N2)(C10H9N3)(CO)(3)], has been corrected. In the present structure, the precision of the Mo-C and Mo-N bond distances for the fac-MoC3N3 centre are significantly improved, and an N atom and a C-H group have been exchanged. Possible intramolecular N-H center dot center dot center dot C and C-H center dot center dot center dot N and intermolecular C-H center dot center dot center dot O interactions are described.
AB - The previous structure report [Howie & McQuillan (1986). J. Chem. Soc. Dalton Trans. pp. 759-764] of the title compound, [Mo(C10H8N2)(C10H9N3)(CO)(3)], has been corrected. In the present structure, the precision of the Mo-C and Mo-N bond distances for the fac-MoC3N3 centre are significantly improved, and an N atom and a C-H group have been exchanged. Possible intramolecular N-H center dot center dot center dot C and C-H center dot center dot center dot N and intermolecular C-H center dot center dot center dot O interactions are described.
U2 - 10.1107/S160053680705461X
DO - 10.1107/S160053680705461X
M3 - Article
SN - 1600-5368
VL - 63
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 12
M1 - m2918
ER -