(2,2 '-bipyridyl)tricarbonyl(di-2-pyridylamine)molybdenum(0) revisited

Kathleen J. Muir, Geoffrey P. McQuillan, William T. A. Harrison

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Abstract

The previous structure report [Howie & McQuillan (1986). J. Chem. Soc. Dalton Trans. pp. 759-764] of the title compound, [Mo(C10H8N2)(C10H9N3)(CO)(3)], has been corrected. In the present structure, the precision of the Mo-C and Mo-N bond distances for the fac-MoC3N3 centre are significantly improved, and an N atom and a C-H group have been exchanged. Possible intramolecular N-H center dot center dot center dot C and C-H center dot center dot center dot N and intermolecular C-H center dot center dot center dot O interactions are described.

Original languageEnglish
Article numberm2918
Number of pages10
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number12
DOIs
Publication statusPublished - Dec 2007

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