2,3-Dihydro-3,3-dimethylspiro[1H-4-oxanthracene-5,2'-oxiran]-10(5H)-one

V. F. Ferreira, A. V. Pinto, M. C. F. R. Pinto, M. N. da Silva, Janet Mabel Scott Skakle, M. C. B. V. de Souza, S. M. S. V. Wardell

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The central six-membered ring in the title compound, C16H16O3, is almost planar (and almost coplanar with the aromatic ring), despite one of its C atoms being formally sp(3) hybridized. The planarity is a consequence of the C atom at the centre of the spirocyclic system also being part of the three-membered epoxide ring. The molecules are linked by pi-pi and C-H ... pi interactions.

Original languageEnglish
Pages (from-to)o560-o562
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC58
DOIs
Publication statusPublished - 2002

Fingerprint

Epoxy Compounds
Atoms
Molecules

Keywords

  • beta-lapachone
  • derivatives
  • naphthoquinones

Cite this

Ferreira, V. F., Pinto, A. V., Pinto, M. C. F. R., da Silva, M. N., Skakle, J. M. S., de Souza, M. C. B. V., & Wardell, S. M. S. V. (2002). 2,3-Dihydro-3,3-dimethylspiro[1H-4-oxanthracene-5,2'-oxiran]-10(5H)-one. Acta Crystallographica Section C, Crystal Structure Communications, C58, o560-o562. https://doi.org/10.1107/S0108270102013665

2,3-Dihydro-3,3-dimethylspiro[1H-4-oxanthracene-5,2'-oxiran]-10(5H)-one. / Ferreira, V. F.; Pinto, A. V.; Pinto, M. C. F. R.; da Silva, M. N.; Skakle, Janet Mabel Scott; de Souza, M. C. B. V.; Wardell, S. M. S. V.

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. C58, 2002, p. o560-o562.

Research output: Contribution to journalArticle

Ferreira, V. F. ; Pinto, A. V. ; Pinto, M. C. F. R. ; da Silva, M. N. ; Skakle, Janet Mabel Scott ; de Souza, M. C. B. V. ; Wardell, S. M. S. V. / 2,3-Dihydro-3,3-dimethylspiro[1H-4-oxanthracene-5,2'-oxiran]-10(5H)-one. In: Acta Crystallographica Section C, Crystal Structure Communications. 2002 ; Vol. C58. pp. o560-o562.
@article{fce3260971a84510b21f58187bf36534,
title = "2,3-Dihydro-3,3-dimethylspiro[1H-4-oxanthracene-5,2'-oxiran]-10(5H)-one",
abstract = "The central six-membered ring in the title compound, C16H16O3, is almost planar (and almost coplanar with the aromatic ring), despite one of its C atoms being formally sp(3) hybridized. The planarity is a consequence of the C atom at the centre of the spirocyclic system also being part of the three-membered epoxide ring. The molecules are linked by pi-pi and C-H ... pi interactions.",
keywords = "beta-lapachone, derivatives, naphthoquinones",
author = "Ferreira, {V. F.} and Pinto, {A. V.} and Pinto, {M. C. F. R.} and {da Silva}, {M. N.} and Skakle, {Janet Mabel Scott} and {de Souza}, {M. C. B. V.} and Wardell, {S. M. S. V.}",
year = "2002",
doi = "10.1107/S0108270102013665",
language = "English",
volume = "C58",
pages = "o560--o562",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - 2,3-Dihydro-3,3-dimethylspiro[1H-4-oxanthracene-5,2'-oxiran]-10(5H)-one

AU - Ferreira, V. F.

AU - Pinto, A. V.

AU - Pinto, M. C. F. R.

AU - da Silva, M. N.

AU - Skakle, Janet Mabel Scott

AU - de Souza, M. C. B. V.

AU - Wardell, S. M. S. V.

PY - 2002

Y1 - 2002

N2 - The central six-membered ring in the title compound, C16H16O3, is almost planar (and almost coplanar with the aromatic ring), despite one of its C atoms being formally sp(3) hybridized. The planarity is a consequence of the C atom at the centre of the spirocyclic system also being part of the three-membered epoxide ring. The molecules are linked by pi-pi and C-H ... pi interactions.

AB - The central six-membered ring in the title compound, C16H16O3, is almost planar (and almost coplanar with the aromatic ring), despite one of its C atoms being formally sp(3) hybridized. The planarity is a consequence of the C atom at the centre of the spirocyclic system also being part of the three-membered epoxide ring. The molecules are linked by pi-pi and C-H ... pi interactions.

KW - beta-lapachone

KW - derivatives

KW - naphthoquinones

U2 - 10.1107/S0108270102013665

DO - 10.1107/S0108270102013665

M3 - Article

VL - C58

SP - o560-o562

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -