2,5-Dichloro-N-(3-methyl-phen-yl)benzenesulfonamide

Shumaila Younas Mughal; Islam Ullah Khan; William T A Harrison; Muneeb Hayat Khan; Muhammad Nadeem Arshad

doi:10.1107/S1600536812032023

2,5-Dichloro-N-(3-methyl-phen-yl)benzenesulfonamide

Shumaila Younas Mughal, Islam Ullah Khan, William T A Harrison, Muneeb Hayat Khan^*, Muhammad Nadeem Arshad

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, C13H11Cl2NO2S, the dihedral angle between the aromatic rings is 76.62 (10)°and the C-S-N-C linkage between the rings adopts a gauche conformation [torsion angle =-51.4 (2)°]. A weak intra-molecular C-H⋯O inter-action closes an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R 2 ²(8) loops.

Original language	English
Article number	02476
Number of pages	7
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Early online date	Aug 2012
DOIs	https://doi.org/10.1107/S1600536812032023
Publication status	Published - Aug 2012

Bibliographical note

The authors are thankful to the Higher Education Commission of Pakistan for providing a grant under the project to strengthen the Materials Chemistry Laboratory at GC University, Lahore.

Keywords

data-to-parameter ratio = 14.8
mean σ(C-C) = 0.005 Å
R factor = 0.052
single-crystal X-ray study
T = 296 K
wR factor = 0.159

Access to Document

10.1107/S1600536812032023Licence: Other

Cite this

@article{918ce3b1ab074fc2b3f041129ef2784f,

title = "2,5-Dichloro-N-(3-methyl-phen-yl)benzenesulfonamide",

abstract = "In the title compound, C13H11Cl2NO2S, the dihedral angle between the aromatic rings is 76.62 (10)°and the C-S-N-C linkage between the rings adopts a gauche conformation [torsion angle =-51.4 (2)°]. A weak intra-molecular C-H⋯O inter-action closes an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R 2 2(8) loops.",

keywords = "data-to-parameter ratio = 14.8, mean σ(C-C) = 0.005 {\AA}, R factor = 0.052, single-crystal X-ray study, T = 296 K, wR factor = 0.159",

author = "Mughal, {Shumaila Younas} and Khan, {Islam Ullah} and Harrison, {William T A} and Khan, {Muneeb Hayat} and Arshad, {Muhammad Nadeem}",

note = "The authors are thankful to the Higher Education Commission of Pakistan for providing a grant under the project to strengthen the Materials Chemistry Laboratory at GC University, Lahore. ",

year = "2012",

month = aug,

doi = "10.1107/S1600536812032023",

language = "English",

volume = "68",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - 2,5-Dichloro-N-(3-methyl-phen-yl)benzenesulfonamide

AU - Mughal, Shumaila Younas

AU - Khan, Islam Ullah

AU - Harrison, William T A

AU - Khan, Muneeb Hayat

AU - Arshad, Muhammad Nadeem

N1 - The authors are thankful to the Higher Education Commission of Pakistan for providing a grant under the project to strengthen the Materials Chemistry Laboratory at GC University, Lahore.

PY - 2012/8

Y1 - 2012/8

N2 - In the title compound, C13H11Cl2NO2S, the dihedral angle between the aromatic rings is 76.62 (10)°and the C-S-N-C linkage between the rings adopts a gauche conformation [torsion angle =-51.4 (2)°]. A weak intra-molecular C-H⋯O inter-action closes an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R 2 2(8) loops.

AB - In the title compound, C13H11Cl2NO2S, the dihedral angle between the aromatic rings is 76.62 (10)°and the C-S-N-C linkage between the rings adopts a gauche conformation [torsion angle =-51.4 (2)°]. A weak intra-molecular C-H⋯O inter-action closes an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R 2 2(8) loops.

KW - data-to-parameter ratio = 14.8

KW - mean σ(C-C) = 0.005 Å

KW - R factor = 0.052

KW - single-crystal X-ray study

KW - T = 296 K

KW - wR factor = 0.159

UR - http://www.scopus.com/inward/record.url?scp=84864691574&partnerID=8YFLogxK

U2 - 10.1107/S1600536812032023

DO - 10.1107/S1600536812032023

M3 - Article

AN - SCOPUS:84864691574

SN - 1600-5368

VL - 68

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

M1 - 02476

ER -

2,5-Dichloro-N-(3-methyl-phen-yl)benzenesulfonamide

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this