(2E)-3-(1,3-Benzodioxol-5-yl)-1-(3-bromo-2-thienyl)prop-2-en-1-one

W. T. A. Harrison; C. S. Chidan Kumar; H. S. Yathirajan; B. V. Ashalatha; B. Narayana

doi:10.1107/S1600536810035129

(2E)-3-(1,3-Benzodioxol-5-yl)-1-(3-bromo-2-thienyl)prop-2-en-1-one

W. T. A. Harrison, C. S. Chidan Kumar, H. S. Yathirajan, B. V. Ashalatha, B. Narayana

Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In the title molecule, C14H9BrO3S, the the prop-2-en-1-one (enone) fragment is close to planar [C-C-C-O = 2.5 (7)degrees] and it subtends dihedral angles of 12.5 (3) and 5.3 (4)degrees with respect to the thiophene and benzene rings, respectively. The dihedral angle between the aromatic ring systems is 12.60 (18)degrees. Two C-H center dot center dot center dot O interactions help to consolidate the non-centrosymmetic crystal packing, which features undulating (100) sheets incorporating C(11) and C(12) chain motifs.

Original language	English
Article number	o2477
Number of pages	9
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	10
DOIs	https://doi.org/10.1107/S1600536810035129
Publication status	Published - Oct 2010

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@article{224a46a99a1d416784b5e1c1b8163c4f,

title = "(2E)-3-(1,3-Benzodioxol-5-yl)-1-(3-bromo-2-thienyl)prop-2-en-1-one",

abstract = "In the title molecule, C14H9BrO3S, the the prop-2-en-1-one (enone) fragment is close to planar [C-C-C-O = 2.5 (7)degrees] and it subtends dihedral angles of 12.5 (3) and 5.3 (4)degrees with respect to the thiophene and benzene rings, respectively. The dihedral angle between the aromatic ring systems is 12.60 (18)degrees. Two C-H center dot center dot center dot O interactions help to consolidate the non-centrosymmetic crystal packing, which features undulating (100) sheets incorporating C(11) and C(12) chain motifs.",

author = "Harrison, {W. T. A.} and Kumar, {C. S. Chidan} and Yathirajan, {H. S.} and Ashalatha, {B. V.} and B. Narayana",

year = "2010",

month = oct,

doi = "10.1107/S1600536810035129",

language = "English",

volume = "66",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "10",

}

TY - JOUR

T1 - (2E)-3-(1,3-Benzodioxol-5-yl)-1-(3-bromo-2-thienyl)prop-2-en-1-one

AU - Harrison, W. T. A.

AU - Kumar, C. S. Chidan

AU - Yathirajan, H. S.

AU - Ashalatha, B. V.

AU - Narayana, B.

PY - 2010/10

Y1 - 2010/10

N2 - In the title molecule, C14H9BrO3S, the the prop-2-en-1-one (enone) fragment is close to planar [C-C-C-O = 2.5 (7)degrees] and it subtends dihedral angles of 12.5 (3) and 5.3 (4)degrees with respect to the thiophene and benzene rings, respectively. The dihedral angle between the aromatic ring systems is 12.60 (18)degrees. Two C-H center dot center dot center dot O interactions help to consolidate the non-centrosymmetic crystal packing, which features undulating (100) sheets incorporating C(11) and C(12) chain motifs.

AB - In the title molecule, C14H9BrO3S, the the prop-2-en-1-one (enone) fragment is close to planar [C-C-C-O = 2.5 (7)degrees] and it subtends dihedral angles of 12.5 (3) and 5.3 (4)degrees with respect to the thiophene and benzene rings, respectively. The dihedral angle between the aromatic ring systems is 12.60 (18)degrees. Two C-H center dot center dot center dot O interactions help to consolidate the non-centrosymmetic crystal packing, which features undulating (100) sheets incorporating C(11) and C(12) chain motifs.

U2 - 10.1107/S1600536810035129

DO - 10.1107/S1600536810035129

M3 - Article

SN - 1600-5368

VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

M1 - o2477

ER -

(2E)-3-(1,3-Benzodioxol-5-yl)-1-(3-bromo-2-thienyl)prop-2-en-1-one

Abstract

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